Acid-catalyzed esterification of free fatty acids with ethanol: an assessment of acid oil pretreatment, kinetic modeling and simulation
Sign Up to like & getrecommendations! Published in 2017 at "Reaction Kinetics, Mechanisms and Catalysis"
DOI: 10.1007/s11144-017-1335-3
Abstract: This work reports experimental data and kinetic modeling of the esterification of different free fatty acids (lauric, stearic, oleic, and also an industrial mixture of fatty acids) with ethanol catalyzed by sulfuric acid. In addition, the… read more here.
Keywords: kinetic modeling; esterification; fatty acids; free fatty ... See more keywords
Kinetic Modeling of the Metal/Support Interaction for CH4 Reaction over Oxidized Pd/Al2O3
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DOI: 10.1007/s11244-018-1125-9
Abstract: This paper deals with the kinetics of CH4 dissociation on model Pd/Al2O3 catalysts. The adsorption and conversion of CH4 over oxidized catalysts, fresh or aged, were studied with a temporal analysis of products (TAP) reactor.… read more here.
Keywords: kinetic modeling; metal support; ch4; interaction ... See more keywords
Towards first-principles based kinetic modeling of biomass fast pyrolysis
Sign Up to like & getrecommendations! Published in 2017 at "Biomass Conversion and Biorefinery"
DOI: 10.1007/s13399-017-0251-0
Abstract: Biomass conversion to chemicals and fuels through fast pyrolysis shows great potential but requires a more fundamental approach for its deployment. To this end, molecular-based kinetic modeling is starting to play a central role in… read more here.
Keywords: kinetic modeling; fast pyrolysis; pyrolysis; biomass ... See more keywords
Biological treatment of slaughterhouse wastewater: kinetic modeling and prediction of effluent
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Environmental Health Science and Engineering"
DOI: 10.1007/s40201-019-00389-4
Abstract: In this study three modeling approaches consisting Modified Stover-Kincannon, multilayer perceptron neural network (MLPANN) and B-Spline quasi interpolation were applied in order to predict effluent of up-flow anaerobic sludge blanket (UASB) reactor and also to… read more here.
Keywords: slaughterhouse wastewater; kinetic modeling; biological treatment; treatment slaughterhouse ... See more keywords
Kinetic modeling of isobutane dehydrogenation over Ga2O3/Al2O3 catalyst
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DOI: 10.1016/j.cej.2019.122741
Abstract: Abstract Kinetic modeling was done for isobutane dehydrogenation using an alumina supported gallia catalyst in a fixed bed reactor at atmosphere pressure, 520–580 °C and a short residence time (ca. 0.06–0.3 s). A complex reaction network was… read more here.
Keywords: kinetic modeling; isobutane dehydrogenation; isobutane; modeling isobutane ... See more keywords
Kinetic modeling of oleic acid esterification with UiO-66: from intrinsic experimental data to kinetics via elementary reaction steps
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2020.124816
Abstract: Abstract This work reports the experimental conversion of oleic acid (OA) into methyl oleate via UiO-66 MOF catalyst. Strong focus is on the kinetic modeling: 67 models, based on elementary reaction steps for Eley-Rideal, Langmuir-Hinshelwood… read more here.
Keywords: kinetic modeling; elementary reaction; reaction steps; oleic acid ... See more keywords
Mechanistic kinetic modeling of simultaneous electrochemical nitrate reduction and ammonium ion oxidation in wastewater
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Engineering Science"
DOI: 10.1016/j.ces.2021.117025
Abstract: Abstract Two kinetic models, i.e., schemes, surface adsorbed nitrogen as divergent (SND) and surface adsorbed NO as divergent (SNOD) towards NH4+ and N2 production, were developed to model simultaneous electrochemical reduction of the nitrate ion… read more here.
Keywords: kinetic modeling; oxidation; mechanistic kinetic; simultaneous electrochemical ... See more keywords
Detailed kinetic modeling of dimethoxymethane. Part II: Experimental and theoretical study of the kinetics and reaction mechanism
Sign Up to like & getrecommendations! Published in 2019 at "Combustion and Flame"
DOI: 10.1016/j.combustflame.2018.12.026
Abstract: Abstract In this study (Part II), the oxidation of dimethoxymethane (DMM) is investigated and a detailed chemical reaction model developed for a comprehensive description of both high- and low-temperature oxidation processes. The sub-mechanism of DMM… read more here.
Keywords: part; kinetic modeling; oxidation; detailed kinetic ... See more keywords
Experimental and kinetic modeling investigation on anisole pyrolysis: Implications on phenoxy and cyclopentadienyl chemistry
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DOI: 10.1016/j.combustflame.2018.12.028
Abstract: Abstract In this work, the flow reactor pyrolysis of anisole was studied at pressures of 0.04 and 1 atm and temperatures from 850 to 1160 K. Comprehensive speciation was achieved using synchrotron vacuum ultraviolet photoionization mass… read more here.
Keywords: kinetic modeling; experimental kinetic; chemistry; pyrolysis ... See more keywords
A chemical kinetic modeling study of indene pyrolysis
Sign Up to like & getrecommendations! Published in 2019 at "Combustion and Flame"
DOI: 10.1016/j.combustflame.2019.04.040
Abstract: Abstract An improved polycyclic aromatic hydrocarbon (PAH) model is developed to predict the decomposition of indene and the formation of large PAHs under pyrolytic conditions. This model is developed based on experimental study of pyrolytic… read more here.
Keywords: pah; pah growth; kinetic modeling; study ... See more keywords
Experimental and kinetic modeling study on 1,3-cyclopentadiene oxidation and pyrolysis
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DOI: 10.1016/j.combustflame.2019.10.032
Abstract: Abstract The oxidation of 1,3-cyclopentadiene (c-C5H6), a key intermediate formed in the combustion of aromatic and cyclic hydrocarbon fuels and formation of polycyclic aromatic hydrocarbons (PAHs), was studied in a jet-stirred reactor (JSR) under the… read more here.
Keywords: kinetic modeling; modeling study; oxidation; experimental kinetic ... See more keywords