Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.
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DOI: 10.1021/acs.chemrev.6b00731
Abstract: Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic kinetic asymmetric transformations. Initially, only enzymes were known to catalyze dynamic kinetic processes, but recently various synthetic… read more here.
Keywords: asymmetric transformations; resolutions dynamic; stereoconvergent catalysis; kinetic asymmetric ... See more keywords
Tailored trisubstituted chiral Cp x RhIII catalysts for kinetic resolutions of phosphinic amides.
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DOI: 10.1039/c7sc05411d
Abstract: A trisubstituted chiral Cp x ligand family is introduced. Based on the disubstituted atropchiral Cp x ligand scaffold, the introduction of a bulky third substituent at the central position of the Cp ring leads to… read more here.
Keywords: tailored trisubstituted; kinetic resolutions; resolutions phosphinic; trisubstituted chiral ... See more keywords