Articles with "kinetic stabilization" as a keyword



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Molecular weight and interfacial effect on the kinetic stabilization of ultrathin polystyrene films

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Published in 2018 at "Polymer"

DOI: 10.1016/j.polymer.2017.11.075

Abstract: Abstract In this article, the kinetic stabilization processes of ultrathin polystyrene (PS) films with different molecular weights (Mw) and interfacial conditions were monitored by controlling the cooling rate. We found that, for the high Mw… read more here.

Keywords: kinetic stabilization; polystyrene films; polymer; kinetic stability ... See more keywords
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Kinetic stabilization allows structural analysis of a benzoborirene.

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Published in 2022 at "Chemical communications"

DOI: 10.1039/d1cc06588b

Abstract: Formal reduction of (2-bromophenyl)chloro(2,2'',4,4'',6,6''-hexaisopropyl-[1,1':3',1''-terphenyl]-2'-yl)borane with tert-butyl lithium at low temperatures yields a highly strained benzoborirene that is kinetically stabilized by the bulky terphenyl substituent. The target compound withstands heating to 80 °C, and represents the… read more here.

Keywords: stabilization allows; analysis benzoborirene; structural analysis; kinetic stabilization ... See more keywords
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Mechanisms of kinetic stabilization by the drugs paclitaxel and vinblastine

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Published in 2017 at "Molecular Biology of the Cell"

DOI: 10.1091/mbc.e16-08-0567

Abstract: Chemotherapeutic agents that target microtubule dynamics promote a universal phenotype of kinetic stabilization. Integrated computational modeling and fluorescence microscopy identify the fundamental kinetic and thermodynamic mechanisms that result in kinetic stabilization, specifically by the drugs… read more here.

Keywords: stabilization; kinetic stabilization; drugs paclitaxel; mechanisms kinetic ... See more keywords
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Generation of an extremely bent pyrene system using kinetic stabilization

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Published in 2017 at "Canadian Journal of Chemistry"

DOI: 10.1139/cjc-2016-0659

Abstract: A series of pyrenophanes was designed with the goal of providing kinetic stabilization to the bent pyrene system and, therefore, providing a means to generate more highly bent pyrene systems than ever before. Four members… read more here.

Keywords: kinetic stabilization; bent pyrene; extremely bent; pyrene system ... See more keywords