A Doubly Kinetically-Gated Information Ratchet Autonomously Driven by Carbodiimide Hydration.
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DOI: 10.1021/jacs.1c01172
Abstract: We report a rotaxane-based information ratchet in which the macrocycle distribution is pumped away from equilibrium using a carbodiimide fuel. A carboxylate group on the axle, nonequidistant between two macrocycle binding sites, efficiently catalyzes the… read more here.
Keywords: doubly kinetically; information ratchet; kinetically gated; macrocycle ... See more keywords