Articles with "kinetics mechanistic" as a keyword



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Kinetics and mechanistic study of polynuclear platinum(II) polypyridyl complexes; A paradigm shift in search of new anticancer agents

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Published in 2018 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2017.08.065

Abstract: Abstract This paper reports on a mechanistic interaction between mononuclear and polynuclear platinum(II) complexes viz; phenyl-dichlorido-2,2′-dipyridinylaminediaquaplatinum(II) (PtC1); di-2-pyridylaminomethylbenzenediaquaplatinum(II) (PtC2); 1,3,5-tris(2,2′dipyridylamino)-benzenehexaquaplatinum(II) (PtC3); 1,3,5-tris(2,2′dipyridylmethylamino)benzenehexaquaplatinum(II) (PtC4); and 2,4,6-tris(2,2′-dipyridylamino)-1,3,5-triazinehexaquaplatinum(II) (PtC5) with thiourea nucleophiles under pseudo-first-order conditions as a function of… read more here.

Keywords: polynuclear platinum; study; mechanistic study; study polynuclear ... See more keywords
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Kinetics and mechanistic study of electrocatalytic hydrogen evolution by [Co(Fc-tpy)2]2+

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Published in 2020 at "Polyhedron"

DOI: 10.1016/j.poly.2020.114677

Abstract: Abstract This paper presents the synthesis and characterization of [Co(Fc-tpy)2](PF6)2 complex which acts as an active electrocatalyst for H2 evolution in both organic and aqueous media (Fc-tpy = 4′-ferrocenyl-2,2′:6′,2″-terpyridine). It exhibits the electrocatalytic H2 evolution in the… read more here.

Keywords: evolution; tpy; mechanistic study; kinetics mechanistic ... See more keywords
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Degradation of Ampicillin and Flucloxacillin Antibiotics via Oxidation by Alkaline Hexacyanoferrate(III): Kinetics and Mechanistic Aspects

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Published in 2020 at "Industrial & Engineering Chemistry Research"

DOI: 10.1021/acs.iecr.0c03956

Abstract: The kinetics and mechanistic aspects of the oxidation of two beta-lactam antibiotics (A), ampicillin and flucloxacillin, by alkaline hexacyanoferrate(III) (HCF(III)) were examined using spectrophot... read more here.

Keywords: iii; alkaline hexacyanoferrate; hexacyanoferrate iii; ampicillin flucloxacillin ... See more keywords
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Kinetics and mechanistic details of bulk ZnO dissolution using a thiol–imidazole system

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Published in 2022 at "Chemical Science"

DOI: 10.1039/d1sc06667f

Abstract: Oxide dissolution is important for metal extraction from ores and has become an attractive route for the preparation of inks for thin film solution deposition; however, oxide dissolution is often kinetically challenging. While binary “alkahest”… read more here.

Keywords: bulk zno; mechanistic details; zno dissolution; kinetics mechanistic ... See more keywords
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Comprehensive Kinetics and a Mechanistic Investigation on the Biological Active Pyrano[2,3-C]Pyrazole Core in the Presence of Both Eco-Friendly Catalyst and Solvent: Experimental Green Protocol

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Published in 2020 at "Polycyclic Aromatic Compounds"

DOI: 10.1080/10406638.2020.1751667

Abstract: Full chemical-kinetics of the green one-pot four-component condensation among ethyl acetoacetate 1, hydrazine hydrate 2, malononitrile 3 and various substituents of benzaldehyde 4 has been spectral... read more here.

Keywords: active pyrano; biological active; kinetics mechanistic; investigation biological ... See more keywords