Modulating intramolecular electron and proton transfer kinetics for promoting carbon dioxide conversion.
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DOI: 10.1039/d1cc06731a
Abstract: A novel pentagon-heptagon paired azulene group that possesses a large dipole moment is immobilized onto a porphyrin. The as-prepared azulene iron porphyrin exhibits a narrower bandgap and higher electrocatalytic CO2 reduction activity than the pristine… read more here.
Keywords: kinetics promoting; proton transfer; electron proton; intramolecular electron ... See more keywords