Total Synthesis of (±)-Pestalachloride C and (±)-Pestalachloride D through a Biomimetic Knoevenagel/Hetero-Diels-Alder Cascade.
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DOI: 10.1021/acs.orglett.9b00323
Abstract: A concise total synthesis of (±)-pestalachloride C and (±)-pestalachloride D was achieved through a Knoevenagel/hetero-Diels-Alder cascade reaction to test the nonenzymatic biosynthetic hypothesis of Shao, Wang, and co-workers. The cascade reaction generates a mixture of… read more here.
Keywords: synthesis pestalachloride; pestalachloride; hetero diels; total synthesis ... See more keywords