Stereostructure Clarifying Total Synthesis of the (Polyenoyl)tetramic Acid Militarinone B. A Highly Acid-Labile N-Protecting Group for Amides†.
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DOI: 10.1021/acs.orglett.1c01652
Abstract: The 5S, 8'R, and 10'R configurations of militarinone B (3), which is a natural product from Paecilomyces militaris, should equal those in its biosynthetic precursor, militarinone C. The configuration at C-1' emerged from syntheses of… read more here.
Keywords: labile protecting; militarinone; acid labile; protecting group ... See more keywords