Complex Magnetic Order in Topochemically Reduced Rh(I)/Rh(III) LaM0.5Rh0.5O2.25 (M = Co, Ni) Phases
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DOI: 10.1021/acs.inorgchem.2c02747
Abstract: Topochemical reduction of the cation-disordered perovskite oxides LaCo0.5Rh0.5O3 and LaNi0.5Rh0.5O3 with Zr yields the partially anion-vacancy ordered phases LaCo0.5Rh0.5O2.25 and LaNi0.5Rh0.5O2.25, respectively. Neutron diffraction and Hard X-ray photoelectron spectroscopy (HAXPES) measurements reveal that the anion-deficient… read more here.
Keywords: complex magnetic; lani0 5rh0; magnetic order; 5rh0 5o2 ... See more keywords