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Published in 2022 at "ACS Catalysis"
DOI: 10.1021/acscatal.1c05689
Abstract: Redox-switching of a formazanate zinc catalyst in ring-opening polymerization (ROP) of lactide is described. Using a redox-active ligand bound to an inert metal ion (Zn2+) allows modulation of the catalytic activity by reversible reduction/oxidation chemistry…
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Keywords:
redox;
lactide cyclopolymerization;
reversible switching;
ligand ... See more keywords