Biomimetic Synthesis of Chejuenolides A–C by a Cryptic Lactone-Based Macrocyclization: Stereochemical Implications in Biosynthesis
Sign Up to like & getrecommendations! Published in 2023 at "ACS Central Science"
DOI: 10.1021/acscentsci.2c01096
Abstract: A hypothetical Mannich macrocyclization in the biosynthesis of chejuenolides A–C served as the basis for the synthetic design herein. Using a lactone-based linear precursor constructed via a tactic sequence of aldol–Julia–aldol reactions on a gram… read more here.
Keywords: synthesis chejuenolides; lactone based; macrocyclization; biomimetic synthesis ... See more keywords