Determination of thermodynamic parameters from Langmuir isotherm constant-revisited
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DOI: 10.1016/j.molliq.2016.11.058
Abstract: Abstract An analytical approach for estimation of the thermodynamic parameters from the Langmuir isotherm constant has been introduced in the present paper. The concept of the thermodynamic equilibrium constant for the Langmuir isotherm based adsorption… read more here.
Keywords: equilibrium constant; thermodynamic parameters; langmuir isotherm; thermodynamic equilibrium ... See more keywords
Predicting equilibrium time by adsorption kinetic equations and modifying Langmuir isotherm by fractal-like approach
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DOI: 10.1016/j.molliq.2018.07.113
Abstract: Abstract In this work, the pseudo-first-order (PFO), pseudo-second-order (PSO) and Vermeulen equations were modified by introducing an adjustable parameter i.e. the fractional surface coverage θ. The Langmuir kinetic equation was modified by the fractal-like approach… read more here.
Keywords: equilibrium time; like approach; fractal like; langmuir isotherm ... See more keywords