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Lantern‐type dinickel complexes: An exploration of possibilities for nickel–nickel bonding with bridging bidentate ligands

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1 Published in 2022 at "Journal of Computational Chemistry"

DOI: 10.1002/jcc.26936

Abstract: Many binuclear nickel complexes have NiNi distances suggesting NiNi covalent bonds, including lantern‐type complexes with bridging bidentate ligands. This DFT study treats tetragonal, trigonal, and digonal lantern‐type complexes with the formamidinate, guanidinate, and formate ligands,… read more here.

Keywords: bridging bidentate; bidentate ligands; lantern type; dinickel complexes ... See more keywords

Bis(triazenide), tris(triazenide), and lantern-type of triazenide iron complexes: Synthesis and structural characterization

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0 Published in 2018 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2018.02.014

Abstract: Abstract A commercially available triazine, PhNNN(H)Ph, served as a monoanionic bidentate ligand upon deprotonation using Fe[N(SiMe3)2]2. By simply using different ethereal solvents, the bis(diethylether) and bis(tetrahydrofurane) complexes of Fe[PhNNNPh]2, 1 and 2, can be prepared… read more here.

Keywords: triazenide tris; bis triazenide; lantern type; bis ... See more keywords