Synthesis of N-Methyl-o-phenylenediamine-Bridged Bis(phenolato) Lanthanide Alkoxides and Their Catalytic Performance for the (Co)Polymerization of rac-Butyrolactone and l-Lactide.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00582
Abstract: A series of lanthanide alkoxo complexes supported by ONNO salalen ligands were synthesized and characterized. A one-pot reaction of LH2 (L = (2-O-C6H2-tBu2-3,5)CH═N-C6H4-N(CH3)CH2(2-O-C6H2-tBu2-3,5)) with LnCp3(THF) in a 1:1 molar ratio followed by the addition of… read more here.
Keywords: spectroscopy; lanthanide alkoxo; alkoxo complexes; rac butyrolactone ... See more keywords