Articles with "lanthanide based" as a keyword



A New Generation of NIR‐II Probes: Lanthanide‐Based Nanocrystals for Bioimaging and Biosensing

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Published in 2019 at "Advanced Optical Materials"

DOI: 10.1002/adom.201801417

Abstract: Recently, fluorescence imaging has been extensively studied and used in life sciences and medical research due to its fast feedback, high sensitivity, and high spatiotemporal resolution.[1–4] In addition, it does not require hazard ionizing radiation,… read more here.

Keywords: new generation; nir; generation nir; penetration depth ... See more keywords

Phytoglycogen Encapsulation of Lanthanide-Based Nanoparticles as an Optical Imaging Platform with Therapeutic Potential.

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Published in 2022 at "Small"

DOI: 10.1002/smll.202107130

Abstract: Lanthanide-based upconverting nanoparticles (UCNPs) are largely sought-after for biomedical applications ranging from bioimaging to therapy. A straightforward strategy is proposed here using the naturally sourced polymer phytoglycogen to coencapsulate UCNPs with hydrophobic photosensitizers as an… read more here.

Keywords: imaging platform; lanthanide based; phytoglycogen; encapsulation ... See more keywords
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Efficient hydrolytic cleavage of phosphodiester with a lanthanide-based metal-organic framework

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Published in 2021 at "Journal of Solid State Chemistry"

DOI: 10.1016/j.jssc.2020.121820

Abstract: Abstract Hydrolysis of phosphate diesters has attracted substantial research efforts, not only in bio-organic chemistry, but also in inorganic chemistry. Herein, a lanthanide-based metal-organic framework was synthesized by incorporating a tetraphenylethylene moiety as the four-point… read more here.

Keywords: cleavage; chemistry; metal organic; based metal ... See more keywords

Multiplexed Biosensing and Bioimaging Using Lanthanide-Based Time-Gated Förster Resonance Energy Transfer.

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Published in 2022 at "Accounts of chemical research"

DOI: 10.1021/acs.accounts.1c00691

Abstract: ConspectusThe necessity to scrutinize more and more biological molecules and interactions both in solution and on the cellular level has led to an increasing demand for sensitive and specific multiplexed diagnostic analysis. Photoluminescence (PL) detection… read more here.

Keywords: lanthanide based; rster resonance; biosensing bioimaging; resonance energy ... See more keywords

Nanotubes from Lanthanide-Based Misfit-Layered Compounds: Understanding the Growth, Thermodynamic, and Kinetic Stability Limits

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Published in 2024 at "Chemistry of Materials"

DOI: 10.1021/acs.chemmater.4c00481

Abstract: Gaining insights into the kinetics and the thermodynamic limits of nanostructures in high-temperature reactions is crucial for controlling their unique morphology, phase, and structure. Nanotubes from lanthanide-based misfit-layered compounds (MLCs) have been known for more… read more here.

Keywords: misfit layered; layered compounds; nanotubes lanthanide; stability ... See more keywords
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Radical-Doped Crystalline Lanthanide-Based Photochromic Complexes: Self-Assembly Driven by Multiple Interactions and Photoswitchable Luminescence.

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Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c01819

Abstract: Stimuli-responsive functional materials, especially the light stimulation color change and tunable fluorescent materials, have received considerable attention because of their broad applications in smart materials. Herein, a series of lanthanide-based [Ln = Nd(III) (1), Sm(III)… read more here.

Keywords: iii iii; self assembly; radical doped; crystalline ... See more keywords

Luminance and Brightness: Application to Lanthanide-Based Coordination Polymers.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c03500

Abstract: Measuring the luminance of lanthanide-based coordination polymers under UV excitation is of prime importance for many technological applications. This study highlights that the quantum yield gives no information about the luminescence intensity of a solid-state… read more here.

Keywords: luminance; lanthanide based; based coordination; luminescence ... See more keywords

Divalent Intermediates in Lanthanide-Based Photocatalysts: Spectroscopic Characterization and Reactivity

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Published in 2024 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.4c03926

Abstract: The reduction of stable trivalent lanthanide species (Ln(III)) by the excited states of organic chromophores is the basis of photocatalytic divalent lanthanide-mediated reduction reactions. While indirect evidence of the photochemical formation of the reactive Ln(II)… read more here.

Keywords: divalent intermediates; based photocatalysts; lanthanide based; divalent ... See more keywords
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Lanthanide-Based Coordination Polymers with a 4,5-Dichlorophthalate Ligand Exhibiting Highly Tunable Luminescence: Toward Luminescent Bar Codes.

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Published in 2018 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.8b00169

Abstract: Reactions in water of 4,5-dichlorophthalate (dcpa2-) with the heaviest lanthanide ions lead to a family of compounds with the general chemical formula [Ln2(dcpa)3(H2O)5·3H2O]∞, where Ln = Tb-Lu, Y. The synthesis, crystal structure, thermal behavior, and… read more here.

Keywords: bar codes; luminescent bar; based coordination; coordination polymers ... See more keywords

Microcrystalline Core-Shell Lanthanide-Based Coordination Polymers for Unprecedented Luminescent Properties.

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Published in 2019 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.8b02815

Abstract: Microcrystalline core-shell powders of lanthanide-based coordination polymers with general chemical formula ([Ln(cpbOH)]∞)1- x@([Ln'(cpbOH)]∞) x with Hcpb = 1,4-carboxyphenylboronic acid have been synthesized and structurally characterized. Their luminescent properties have been studied. They are drastically different… read more here.

Keywords: coordination; core shell; based coordination; coordination polymers ... See more keywords

Two-Dimensional Half-Metallic and Semiconducting Lanthanide-Based MXenes

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Published in 2022 at "ACS Omega"

DOI: 10.1021/acsomega.2c03964

Abstract: As a large family of two-dimensional materials, MXenes have attracted intensive attention in recent years. For more functional applications, it is of great significance to determine new MXene members. Here, we theoretically expand the M… read more here.

Keywords: lanthanide based; half metallic; based mxenes; two dimensional ... See more keywords