Generalized synthesis of NaLn(MoO4)2 nano/microcrystals (Ln = La–Lu and Y): The effects of lanthanide contraction, structure, and down-/up-conversion luminescence
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Alloys and Compounds"
DOI: 10.1016/j.jallcom.2020.154676
Abstract: Abstract Systematic synthesis of scheelite-type double molybdate nano-/microcrystals NaLn (MoO4)2 (Ln = La–Lu lanthanides and Y) was successfully carried out via hydrothermal reaction at 180 °C without using any organic additive, and the intrinsic effects of lanthanide contraction… read more here.
Keywords: lanthanide contraction; nano microcrystals; luminescence; naln moo4 ... See more keywords
The Lanthanide Contraction Is a Variable.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00261
Abstract: Upon examination of the bond distances of the recently reported series of [Ln(SST)3(THF)2] [Ln = lanthanides, SST = tris(trimethylsilyl)siloxide (OSi(SiMe3)3), and THF = tetrahydrofuran] compounds, it was found that over the Ln-series (La through Lu),… read more here.
Keywords: lanthanide contraction; sst thf; contraction; bond ... See more keywords
Lanthanide Contraction: What is Normal?
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DOI: 10.1021/acs.inorgchem.2c03674
Abstract: Renewed interest in lanthanide contraction results from its possible effect on the properties and applications of Ln(III) compounds and the theory related to these issues. To understand this effect, it is important to know what… read more here.
Keywords: lanthanide contraction; contraction normal; contraction; chemistry ... See more keywords
Tuning dimensionality between 2D and 1D MOFs by lanthanide contraction and ligand-to-metal ratio
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DOI: 10.1039/d0nj04055j
Abstract: 2D/1D dimensionality tuning in LnMOFs is related to both (i) ligand-to-metal ratio and (ii) lanthanide contraction, this is only possible with Er/Tm, lighter lanthanides e.g. Pr only produced 2D MOFs, despite different ligand-to-metal ratios were… read more here.
Keywords: ligand metal; ligand; lanthanide contraction; metal ratio ... See more keywords
Lanthanum and Lanthanide Trifluorides: Lanthanide Contraction and Volume of Fluorine Ion
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DOI: 10.1134/s1063774520020212
Abstract: Abstract Lanthanide contraction of lanthanum and 14 lanthanides ( Ln ), leading to a decrease in R 3+ ionic radii by ~15% (with respect to the smallest one) with an increase in the element atomic… read more here.
Keywords: lanthanide contraction; volume; value; contraction ... See more keywords