Sensitive luminescent probes of aniline, benzaldehyde and Cr(VI) based on a zinc(II) metal-organic framework and its lanthanide(III) post-functionalizations
Sign Up to like & getrecommendations! Published in 2018 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2018.07.005
Abstract: Abstract A novel zinc(II) metal-organic framework (MOF) {[(CH3)2NH2]2 [Zn5 (TDA)4 (TZ)4].4DMF}n (1) (H2TDA = thiophene-2,5-dicarboxylic acid and HTZ = 1H-1,2,4-Triazole) based on Zn5(COO)2 (TZ)4 pentametallic clusters and thiophene-2,5-dicarboxylic acid was synthesized and structurally characterized via the mixed-ligand strategy. This… read more here.
Keywords: zinc metal; framework; luminescent probes; aniline benzaldehyde ... See more keywords
Biological properties of a new mixed lanthanide(III) complex incorporating a dypiridinium ylide
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119517
Abstract: Abstract A new mixed lanthanide(III) complex [LaNd(μ2-DPY)(μ4-SO4)2(Et3N)]Br2·2H2OMeOH (La-Nd-DPY) was obtained by the reaction of N,N′-diphenacyl-4,4′-dipyridinium dibromide (DPB) with a mixture of La(III) and Nd(III) sulfates in a 2:1 M ratio, in the presence of triethylamine (Et3N).… read more here.
Keywords: new mixed; iii; mixed lanthanide; dpy ... See more keywords
Near-infrared emitting probes for biological imaging: Organic fluorophores, quantum dots, fluorescent proteins, lanthanide(III) complexes and nanomaterials
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2016.09.058
Abstract: Abstract Fluorescence optical imaging is a highly sensitive and powerful tool with diverse in vitro and in vivo applications for preclinical and clinical studies. This review is focused on the optical imaging in the near-infrared… read more here.
Keywords: organic fluorophores; lanthanide iii; fluorescent proteins; near infrared ... See more keywords
Lanthanide nitrato complexes bridged by the bis-tridentate ligand 2,3,5,6-tetra(2-pyridyl)pyrazine: Syntheses, crystal structures, Hirshfeld surface analyses, luminescence properties, DFT calculations, and magnetic behavior.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of luminescence"
DOI: 10.1016/j.jlumin.2020.117835
Abstract: Six dinuclear lanthanide(III) nitrato complexes [Ln(NO3)3(H2O)]2(μ-tppz) (where tppz = 2,3,5,6-tetra(2-pyridyl) pyrazine and Ln(III) = Nd (1), Sm (2), Eu (3), Gd (4), Tb (5), and Dy (6)) with bis-tridentate N-heterocyclic 2,3,5,6-tetra(2-pyridyl)pyrazine as bridging ligand have… read more here.
Keywords: tetra pyridyl; lanthanide iii; luminescence; pyridyl pyrazine ... See more keywords
Four novel lanthanide(III) coordination complexes based on 3,4,5-trifluorobenzeneseleninic acid
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2018.11.035
Abstract: Abstract Four novel isostructural lanthanide coordination complexes [Ln2(L)6(DMF)]n (Ln = Nd (1), Tb (2), Dy (3), Ho (4)) were successfully assembled under hydrothermal conditions with Ln3+ salts and 3,4,5-trifluorobenzeneseleninic acid (HL). All the complexes have… read more here.
Keywords: coordination complexes; four novel; trifluorobenzeneseleninic acid; lanthanide iii ... See more keywords
Magnetooptical Properties of Lanthanide(III) Metal-Organic Frameworks Based on an Iridium(III) Metalloligand.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03322
Abstract: Integrating magnetic and optical properties into a metal-organic framework (MOF) remains a great challenge. Herein, we have reasonably constructed two 3D magnetooptical MOFs by incorporating a [IrIII(ppy)2(bpy)]+-based fluorescent metalloligand and magnetic LnIII centers. The alternating… read more here.
Keywords: lanthanide iii; properties lanthanide; iii metal; organic frameworks ... See more keywords
Gold(I)···Lanthanide(III) Bonds in Discrete Heterobimetallic Compounds: A Combined Computational and Topological Study
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c02717
Abstract: The chemical nature of the ligand-unsupported gold(I)–lanthanide(III) bond in the proposed [LnIII(η5-Cp)2][AuIPh2] (Ln–Au; LnIII = LaIII, EuIII, or LuIII; Cp = cyclopentadienide; Ph = phenyl) models is examined from a theoretical viewpoint. The covalent bond-like… read more here.
Keywords: lanthanide iii; iii bonds; gold lanthanide; bond ... See more keywords
Functionalized Lanthanide(III) Complexes Constructed from Azobenzene Derivative and β-Diketone Ligands: Luminescent, Magnetic, and Reversible Trans-to-Cis Photoisomerization Properties.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02819
Abstract: The coordination ability of ligands functionalized by azobenzene was manipulated, and two novel chelating ligands, (E)-4-(phenyldiazenyl)-N,N-bis(pyridin-2-ylmethyl) benzohydrazide (C25H22N6O, PBPM) and (E)-4-((4-(dimethylamino)phenyl)diazenyl)-N,N-bis(pyridin-2-ylmethyl) benzohydrazide (C27H27N7O, dmPBPM), were synthesized. The ligands can offer four coordinating atoms (one oxygen… read more here.
Keywords: lanthanide iii; trans cis; iii complexes; cf3co2 ... See more keywords
Complexation of Actinide(III) and Lanthanide(III) with H4TPAEN for a Separation of Americium from Curium and Lanthanides.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00603
Abstract: Previous studies have identified the TPAEN ligand as a potentially appropriate complexing agent in solvent extraction processes for the separation of americium (Am(III)) from the fission products including lanthanide (Ln(III)) and curium (Cm(III)) ions, a… read more here.
Keywords: iii; lanthanide iii; actinide iii; complexation ... See more keywords
Theoretical Determination of Energy Transfer Processes and Influence of Symmetry in Lanthanide(III) Complexes: Methodological Considerations.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00159
Abstract: This work presents a theoretical protocol to analyze the symmetry effect on the allowed character of the transitions and to estimate the probability of energy transfer in lanthanide(III) complexes. For this purpose, a complete study… read more here.
Keywords: energy transfer; energy; lanthanide iii; iii complexes ... See more keywords
Lanthanide(III)-Based Single-Ion Magnets
Sign Up to like & getrecommendations! Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b01204
Abstract: Mononuclear lanthanide-based single-ion magnets (SIMs) are known since 2003 with the discovery of SIM properties in a bis-(phthalocyaninato)lanthanide complex. A recent report on [Dy(Cpttt)2][BC6F5] indicating that it exhibits the highest known blocking temperature (60 K)… read more here.
Keywords: single ion; lanthanide iii; based single; ion magnets ... See more keywords