DFT study of 2,9-bis(1,2,4-triazin-3-yl)-1,10-phenanthroline (BTPhen) and its derivatives complexation with lanthanide series
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DOI: 10.1016/j.comptc.2020.112729
Abstract: Abstract The complexation reactions between lanthanide 3+ cations and 2,9-bis(1,2,4-triazin-3-yl)-1,10-phenanthroline and its derivatives were studied with density functional theory Perdew-Burke-Ernzerhof functionals. The complexes consisted of one lanthanide cation and two ligand molecules. Complexation reactions were… read more here.
Keywords: triazin phenanthroline; lanthanide series; series; dft study ... See more keywords
Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C5Me4H)3Ln] Complexes
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DOI: 10.1021/acs.organomet.8b00557
Abstract: Although previous studies of the stabilization of Ln(II) ions across the lanthanide series have relied on Me3Si-substituted cyclopentadienyl ligands, we now find surprisingly that these ions can also exist surrounded by three tetramethylcyclopentadienyl ligands. Reduction… read more here.
Keywords: across lanthanide; tetramethylcyclopentadienyl ligands; ions across; lanthanide series ... See more keywords