A Series of 3D Porous Lanthanide-Substituted Polyoxometalate Frameworks Based on Rare Hexadecahedral {Ln6W8O28} Heterometallic Cage-Shaped Clusters.
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DOI: 10.1021/acs.inorgchem.9b02413
Abstract: A series of 3D porous lanthanide-substituted polyoxometalate frameworks, Na2[Ln2(H2O)11]2[Ln3(H2O)3(α-SiW11O39)2]2·69H2O (1-Ln, Ln = Sm, Eu, Gd, Tb, and Dy), are built from novel hexadecahedral {Ln6W8O28} heterometallic cage-shaped clusters. Intriguingly, every tetrameric {[Ln3(H2O)3(α-SiW11O39)2]2}14- cage-cluster is linked with… read more here.
Keywords: series porous; porous lanthanide; substituted polyoxometalate; lanthanide substituted ... See more keywords
Ce(OH)2Cl and lanthanide-substituted variants as precursors to redox-active CeO2 materials.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt03435e
Abstract: The cerium(iii) hydroxide chloride Ce(OH)2Cl crystallises directly as a polycrystalline powder from a solution of CeCl3·7H2O in poly(ethylene) glycol (Mn = 400) heated at 240 °C and is found to be isostructural with La(OH)2Cl, as… read more here.
Keywords: variants precursors; 2cl lanthanide; precursors redox; substituted variants ... See more keywords