NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge.
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DOI: 10.1021/acs.inorgchem.2c02379
Abstract: A new sodium hydroxyfluorooxoborate, NaB3O4F(OH) (NBOFH), was discovered and synthesized. NBOFH features the unprecedented [B3O4F(OH)] infinite chain constructed by the novel fundamental building block (FBB) of [B3O5F(OH)]. NBOFH has a large birefringence of 0.097 at… read more here.
Keywords: large birefringence; ultraviolet cutoff; short ultraviolet; cutoff edge ... See more keywords
RbNa(HC3N3O3)·2H2O exhibiting a strong second harmonic generation response and large birefringence as a new potential UV nonlinear optical material
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DOI: 10.1039/c9qi01198f
Abstract: A new mixed alkali hydro-isocyanurate, RbNa(HC3N3O3)·2H2O, with the noncentrosymmetric space group Pna21 (No. 33), has been successfully grown by a hydrothermal method. The structure can be described as 2D wavy [Na(HC3N3O3)O4]∞ layers separated by Rb… read more here.
Keywords: rbna hc3n3o3; large birefringence; 2h2o exhibiting; hc3n3o3 2h2o ... See more keywords
RbB3O4F2: a rubidium fluorooxoborate with an unprecedented [B3O5F2]3- functionalized unit and a large birefringence.
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DOI: 10.1039/d0cc06851a
Abstract: A new rubidium fluorooxoborate, RbB3O4F2, was structurally designed and synthesized by using the strategy of fluorine-introduction into borates. Interestingly, RbB3O4F2 presents the novel [B3O4F2]- chains formed by the unprecedented [B3O5F2]3- fundamental building block. More importantly,… read more here.
Keywords: b3o5f2; unprecedented b3o5f2; rubidium fluorooxoborate; large birefringence ... See more keywords
Hydroisocyanurates X2Y(H2C3N3O3)4·4H2O (X = K, Cs; Y = Zn, Cd) with large birefringence stemming from π-conjugated (H2C3N3O3)− anions
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DOI: 10.1039/d0ce00094a
Abstract: Birefringent crystals, critical for the polarization of light, play an important role in the optoelectronics field. Herein, by introducing d10 cations into the structures, a family of hydroisocyanurates, X2Y(H2C3N3O3)4·4H2O (X = K, Cs; Y =… read more here.
Keywords: hydroisocyanurates x2y; conjugated h2c3n3o3; h2c3n3o3 4h2o; x2y h2c3n3o3 ... See more keywords
An antimony(iii) borate with large birefringence exhibiting unwonted [B5O11] fundamental building blocks and dimeric [Sb2O6] clusters
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DOI: 10.1039/d1qi00201e
Abstract: By combining π-conjugated [B3O6] groups and Sb3+ cations with SCALP, we successfully obtained the second antimony(iii) borate SbB5O9 with a large birefringence (0.151 @ 1064 nm), which exhibits unwonted [B5O11] FBBs and dimeric [Sb2O6] clusters. read more here.
Keywords: antimony iii; dimeric sb2o6; unwonted b5o11; iii borate ... See more keywords
KF·B(OH)3: a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency.
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DOI: 10.1039/d2cc03495f
Abstract: A designed material with large birefringence and remarkable deep-ultraviolet transparency, KF·B(OH)3, has been discovered. The well-aligned [F·B(OH)3]- layers endow a very large bandgap (7.63 eV), comparably large birefringence (0.114 @1064 nm), and the reinforced interlayer… read more here.
Keywords: large birefringence; birefringence remarkable; birefringence; deep ultraviolet ... See more keywords