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Published in 2025 at "Advanced Optical Materials"
DOI: 10.1002/adom.202501338
Abstract: Conventional nonpolar nematic liquid crystals, widely known for their successful display applications, are not well suited for fast electro‐optical switching because of the slow (milliseconds) field‐off relaxation of the director. In this work, sub‐microsecond field‐on…
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Keywords:
field;
switching large;
birefringence;
large birefringence ... See more keywords
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Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02379
Abstract: A new sodium hydroxyfluorooxoborate, NaB3O4F(OH) (NBOFH), was discovered and synthesized. NBOFH features the unprecedented [B3O4F(OH)] infinite chain constructed by the novel fundamental building block (FBB) of [B3O5F(OH)]. NBOFH has a large birefringence of 0.097 at…
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Keywords:
large birefringence;
ultraviolet cutoff;
short ultraviolet;
cutoff edge ... See more keywords
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Published in 2024 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c00442
Abstract: The discovery of novel organic-inorganic hybrid nonlinear optical (NLO) crystal materials holds great potential in advancing laser science and technology as they offer a wide range of benefits including easy synthesis, structural versatility, and high…
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Keywords:
moderate second;
acentric based;
birefringence;
two acentric ... See more keywords
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Published in 2024 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c03167
Abstract: In modern optics, birefringent materials that can manipulate light polarization play important roles in lasers and information fields. The search for ultraviolet (UV) crystals with large birefringence is the focus of attention in the field…
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Keywords:
c2h12n6c4o4 2h2o;
3h2o two;
na2c4o4 3h2o;
2h2o na2c4o4 ... See more keywords
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Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c05604
Abstract: To design new nonlinear optical (NLO) crystals efficiently, mixing two or more types of functional groups is a favored strategy. Herein, by combining two types of planar π-conjugate groups, triangular (BO3)3- and square (C4O4)2-, the…
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Keywords:
nonlinear optical;
borate;
borate squarate;
large birefringence ... See more keywords
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Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c02960
Abstract: The combination of two types of NLO-active units into one compound is beneficial to produce outstanding second harmonic generation (SHG) crystals. Herein, by incorporation of Sb3+ with SCALP electrons into planar π-conjugated 2-(aminomethyl)pyridine, two new…
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Keywords:
based nonlinear;
designing hybrid;
large birefringence;
hybrid based ... See more keywords
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Published in 2020 at "Inorganic chemistry frontiers"
DOI: 10.1039/c9qi01198f
Abstract: A new mixed alkali hydro-isocyanurate, RbNa(HC3N3O3)·2H2O, with the noncentrosymmetric space group Pna21 (No. 33), has been successfully grown by a hydrothermal method. The structure can be described as 2D wavy [Na(HC3N3O3)O4]∞ layers separated by Rb…
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Keywords:
rbna hc3n3o3;
large birefringence;
2h2o exhibiting;
hc3n3o3 2h2o ... See more keywords
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Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc06851a
Abstract: A new rubidium fluorooxoborate, RbB3O4F2, was structurally designed and synthesized by using the strategy of fluorine-introduction into borates. Interestingly, RbB3O4F2 presents the novel [B3O4F2]- chains formed by the unprecedented [B3O5F2]3- fundamental building block. More importantly,…
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Keywords:
b3o5f2;
unprecedented b3o5f2;
rubidium fluorooxoborate;
large birefringence ... See more keywords
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Published in 2020 at "CrystEngComm"
DOI: 10.1039/d0ce00094a
Abstract: Birefringent crystals, critical for the polarization of light, play an important role in the optoelectronics field. Herein, by introducing d10 cations into the structures, a family of hydroisocyanurates, X2Y(H2C3N3O3)4·4H2O (X = K, Cs; Y =…
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Keywords:
hydroisocyanurates x2y;
conjugated h2c3n3o3;
h2c3n3o3 4h2o;
x2y h2c3n3o3 ... See more keywords
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Published in 2021 at "Inorganic chemistry frontiers"
DOI: 10.1039/d1qi00201e
Abstract: By combining π-conjugated [B3O6] groups and Sb3+ cations with SCALP, we successfully obtained the second antimony(iii) borate SbB5O9 with a large birefringence (0.151 @ 1064 nm), which exhibits unwonted [B5O11] FBBs and dimeric [Sb2O6] clusters.
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Keywords:
antimony iii;
dimeric sb2o6;
unwonted b5o11;
iii borate ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03495f
Abstract: A designed material with large birefringence and remarkable deep-ultraviolet transparency, KF·B(OH)3, has been discovered. The well-aligned [F·B(OH)3]- layers endow a very large bandgap (7.63 eV), comparably large birefringence (0.114 @1064 nm), and the reinforced interlayer…
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Keywords:
large birefringence;
birefringence remarkable;
birefringence;
deep ultraviolet ... See more keywords