1,3-N,O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Society reviews"
DOI: 10.1039/c6cs00715e
Abstract: 1,3-N,O-Chelating ligands are ubiquitous in nature owing to their occurrence as α-chiral amino acids in metalloproteins. These structural units also display diverse coordination modes, which lend themselves to applications in catalysis as well as novel… read more here.
Keywords: late transition; transition; metals ligands; transition metals ... See more keywords
Late transition metal catalyzed α-olefin polymerization and copolymerization with polar monomers
Sign Up to like & getrecommendations! Published in 2017 at "Materials Chemistry Frontiers"
DOI: 10.1039/c7qm00321h
Abstract: In this review, recent developments on late transition metal catalyzed α-olefin polymerization and copolymerization with polar comonomers are described. First, the polymerization mechanisms of early and late transition metal catalyzed α-olefin polymerization are compared. Second,… read more here.
Keywords: late transition; polymerization; transition metal; metal catalyzed ... See more keywords
Late transition metal oxides with infinite-layer structure: Nickelates versus cuprates
Sign Up to like & getrecommendations! Published in 2020 at "Physical Review B"
DOI: 10.1103/physrevb.101.081110
Abstract: The correlated electronic structure of the infinite-layer compounds ${\mathrm{NdNiO}}_{2}$ and ${\mathrm{SrCuO}}_{2}$ at stoichiometry and with finite hole doping is compared. Key differences are elucidated from an advanced first-principles many-body perspective. Contrary to the charge-transfer insulating… read more here.
Keywords: infinite layer; mathrm; ensuremath; structure ... See more keywords
Tunable Late-Transition-Metal-Catalyzed Polymerization for Controlled Polymer Synthesis
Sign Up to like & getrecommendations! Published in 2023 at "Catalysts"
DOI: 10.3390/catal13040670
Abstract: As a powerful protocol for the preparation of common polymers, such as polyolefins, polyesters, and polycarbonates, late-transition-metal-catalyzed polymerization can be carried out by controlling the reaction conditions or developing dynamic catalytic systems that use external… read more here.
Keywords: late transition; catalyzed polymerization; transition metal;
Tailoring Nanoadsorbent Surfaces: Separation of Rare Earths and Late Transition Metals in Recycling of Magnet Materials
Sign Up to like & getrecommendations! Published in 2022 at "Nanomaterials"
DOI: 10.3390/nano12060974
Abstract: Novel silica-based adsorbents were synthesized by grafting the surface of SiO2 nanoparticles with amine and sulfur containing functional groups. Produced nanomaterials were characterized by SEM-EDS, AFM, FTIR, TGA and tested for adsorption and separation of… read more here.
Keywords: late transition; separation rare; tailoring nanoadsorbent; transition metals ... See more keywords