Ir-Catalyzed Biomimetic Photoisomerization of Cyclopropane in Lathyrane-Type Euphorbia Diterpenes.
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DOI: 10.1021/acs.orglett.2c03172
Abstract: An efficient Ir-catalyzed biomimetic method for photoisomerization of cyclopropane in lathyrane-type Euphorbia diterpenes is reported. Lathyrane diterpenes featuring the trans-fused cyclopropane (1a-5a) were successfully prepared from cis-cyclopropane lathyranes (1-5) in excellent yields by this stereochemical… read more here.
Keywords: cyclopropane; lathyrane type; lathyrane; photoisomerization cyclopropane ... See more keywords