Poly-p-hydroquinone Ethers: Isoenergetic Molecular Wires with Length-Invariant Oxidation Potentials and Cation Radical Excitation Energies.
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DOI: 10.1021/jacs.7b01226
Abstract: Typical poly-p-phenylene wires are characterized by strong interchromophoric electronic coupling with redox and optical properties being highly length-dependent. Herein we show that an incorporation of a pair of para-methoxy groups at each p-phenylene unit in… read more here.
Keywords: invariant oxidation; potentials cation; length invariant; oxidation potentials ... See more keywords