Insights at the molecular level into the formation of oxo-bridged trinuclear uranyl complexes.
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DOI: 10.1039/d1cc06310c
Abstract: Reaction of 1,3,4,6-tetra-O-acetyl-N-(2-hydroxy)-naphthylidene glucosamine (HL(Ac)) with uranyl acetate in ethanol leads to formation of dinuclear [(UO2)2(L)2] (1). In a second step 1 is quantitatively transferred into the trinuclear oxo-bridged complex [(UO2)3(μ3-O)(L)3]2- (22-) via deprotonation and… read more here.
Keywords: level formation; insights molecular; oxo bridged; formation ... See more keywords