Transition Metal Cooperative Lewis Pairs Using Platinum(0) Diphosphine Monocarbonyl Complexes as Lewis bases
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DOI: 10.1021/acs.organomet.9b00568
Abstract: The platinum(0)-diphosphine complex [Pt(CO)(L1)] (3, where L1 = 1,2-C6H4(CH2PtBu2)2) and its diphosphinite analogue [Pt(CO)(L2)] (11, where L2 = 1,2-C6H4(OPtBu2)2) act as Lewis bases in conjunction... read more here.
Keywords: metal cooperative; lewis bases; platinum diphosphine; transition metal ... See more keywords
Modulating Performance and Stability of Inorganic Lead-Free Perovskite Solar Cells via Lewis-pair mediation.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c06971
Abstract: Fully inorganic perovskites based on Bi3+ and Sb3+ are emerging as alternatives that overcome the toxicity and low stability of their Pb-based perovskite counterparts. Nevertheless, thin film fabrication of Pb-free perovskites remains a struggle, with… read more here.
Keywords: modulating performance; lewis bases; perovskite solar; stability ... See more keywords
Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b12998
Abstract: Equilibrium constants for the associations of 17 diaryliodonium salts Ar2I+X- with 11 different Lewis bases (halide ions, carboxylates, p-nitrophenolate, amines, and tris(p-anisyl)phosphine) have been investigated by titrations followed by photometric or conductometric methods as well… read more here.
Keywords: lewis bases; iodonium ions; lewis; diaryliodonium ... See more keywords
Co-crystallization of 1,3,5-trifluoro-2,4,6-triiodobenzene (1,3,5-TFTIB) with a variety of Lewis bases through halogen-bonding interactions
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DOI: 10.1039/c7ce01284e
Abstract: The halogen bond is emerging as an important driving force for supramolecular self-assembly, and has attracted great interest in the past decade. Among the ample halogen-bonding donors, we note the ability of 1,3,5-trifluoro-2,4,6-triiodobenzene (1,3,5-TFTIB) to… read more here.
Keywords: trifluoro triiodobenzene; lewis bases; triiodobenzene tftib; halogen bonding ... See more keywords
The Importance of Strain (Preorganization) in Beryllium Bonds
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DOI: 10.3390/molecules25245876
Abstract: In order to explore the angular strain role on the ability of Be to form strong beryllium bonds, a theoretical study of the complexes of four beryllium derivatives of ortho closo-carboranes with eight molecules (CO,… read more here.
Keywords: beryllium derivatives; lewis bases; ortho carboranes; beryllium bonds ... See more keywords