Immobilization of Lewis Basic Sites into a Quasi‐Molecular‐Sieving Metal–Organic Framework for Enhanced C3H6/C3H8 Separation
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202406664
Abstract: Controlling gas sorption through pore engineering is indispensable in molecular recognition and separation processes. The challenge lies in developing high‐efficiency adsorbents for C3H6/C3H8 separation, specifically enhancing the affinity toward C3H6 for high selectivity while maintaining… read more here.
Keywords: basic sites; separation; c3h8 separation; c3h6 c3h8 ... See more keywords
Lanthanide−Organic complex with uncoordinated lewis basic triazolyl sites as multi-responsive sensor for nitrobenzene, Cu2+ and MnO4−
Sign Up to like & getrecommendations! Published in 2021 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2020.108930
Abstract: Abstract Ln-coordination polymer {Tb(BTTA)1.5(H2O)4.5]n (Tb-1) was successfully obtained via solvo-thermal reaction of Tb(NO3)3⋅6H2O and 2,5-bis-(1H-1,2,4-triazol-1-yl) terephthalic acid (H2BTTA). The measurement of single-crystal X-ray diffraction exhibits that complex Tb-1 displays two-dimensional lay-by-lay frameworks with one-dimensional channels… read more here.
Keywords: lewis basic; organic complex; lanthanide organic; cu2 mno4 ... See more keywords
Copper-Based Bio-MOF/GO with Lewis Basic Sites for CO2 Fixation into Cyclic Carbonates and C-C Bond-Forming Reactions.
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c02036
Abstract: Several measures, including crude oil recovery improvement and carbon dioxide (CO2) conversion into valuable chemicals, have been considered to decrease the greenhouse effect and ensure a sustainable low-carbon future. The Knoevenagel condensation and CO2 fixation… read more here.
Keywords: lewis basic; bio mof; bio; co2 fixation ... See more keywords
Efficient C2Hn Hydrocarbons and VOC Adsorption and Separation in an MOF with Lewis Basic and Acidic Decorated Active Sites.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c12992
Abstract: To help address efficient separation of C2Hn light hydrocarbons and C2H2/CO2 in the chemical industry, the self-assembly via an azolate-carboxylate ligand and Co(II) ion gave rise to a new porous MOF material, [Co(btzip)(H2btzip)]·2DMF·2H2O (1) (H2btzip… read more here.
Keywords: lewis basic; adsorption; c2hn hydrocarbons; mof ... See more keywords
Sonochemical synthesis of microscale Zn(ii)-MOF with dual Lewis basic sites for fluorescent turn-on detection of Al3+ and methanol with low detection limits.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt01175d
Abstract: The effects of synthetic methods, modulator types, the content of the modulator, and reaction time on the size and morphology of a microscale Zn-MOF containing dual Lewis basic amino and carbonyl groups, namely [Zn(NH2-bdc)(4,4'-bpy)] {NH2-H2bdc… read more here.
Keywords: lewis basic; detection; mof; microscale mof ... See more keywords
Highly stable Zn-MOF with Lewis basic nitrogen sites for selective sensing of Fe3+ and Cr2O7 2− ions in aqueous systems
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1830976
Abstract: Abstract A luminescent Zn(II)-based MOF, [Zn(dptz)(BDC)(H2O)]n [1, dptz = 3,6-di(1H-pyrazol-4-yl)-1,2,4,5-tetrazine, H2BDC = terephthalic acid], with Lewis basic nitrogen sites has been synthesized by a solvothermal method. Using ligands with higher pK a value, complex 1 exhibits excellent… read more here.
Keywords: lewis basic; fe3 cr2o7; basic nitrogen; cr2o7 ... See more keywords