Frustrated Lewis Pairs on Zr Single Atoms Supported N‐Doped TiO2‐x Catalysts for Electrochemical Nitrate Reduction To Ammonia
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202401094
Abstract: The electrochemical reduction of nitrates (NO3RR) for ammonia synthesis at room temperature holds immense potential. One key challenge is the adsorption and activation of NO3−, along with the provision of sufficient active hydrogen to accelerate… read more here.
Keywords: single atoms; frustrated lewis; pairs single; lewis pairs ... See more keywords
Frustrated Lewis Pairs Boosting Electrochemical Production of Hydrogen Peroxide on Bi‐TiO2−x Nanocatalysts
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DOI: 10.1002/adfm.202504833
Abstract: Electrocatalytic two‐electron oxygen reduction (2e− ORR) offers an environmentally friendly route for H2O2 production, yet faces challenges in O2 activation and *OOH intermediate stabilization. Here, Bi‐TiO2−x nanocatalysts are introduced featuring frustrated Lewis acid‐base pairs (FLPs)… read more here.
Keywords: frustrated lewis; tio2 nanocatalysts; pairs boosting; boosting electrochemical ... See more keywords
Preparation of Magnetically Recyclable MIL‐101‐immobilized Frustrated Lewis Pairs for the Reduction of Aldehydes and Ketones
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DOI: 10.1002/cctc.202400605
Abstract: Frustrated Lewis pairs (FLPs), composed of spatially hindered Lewis acids and bases, are promising catalysts for the catalytic hydrogenation of unsaturated organic substrates, but the lack of reusability limits their development. The functionalization of solid… read more here.
Keywords: frustrated lewis; mil 101; lewis pairs; magnetically recyclable ... See more keywords
Activation of Small Molecules by Readily Accessible Alkylborane‐based Frustrated Lewis Pairs
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DOI: 10.1002/ejic.202500104
Abstract: Herein, we report that sterically encumbered (thio)imidazolones react with simple aliphatic boranes, such as 9‐borabicyclo[3.3.1]nonane ([H‐B‐9‐BBN]2) or dicyclohexylborane (HBCy2), at room temperature to form (thio)imidazolonate boranes, which function as intramolecular Frustrated Lewis Pairs (FLPs). Although… read more here.
Keywords: activation small; frustrated lewis; molecules readily; activation ... See more keywords
Boron based intramolecular heterocyclic frustrated Lewis pairs as organocatalysts for CO2 adsorption and activation
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26949
Abstract: The massive increase in the amount of carbon dioxide (CO2) in the atmosphere has led to serious environmental problems. One of the best ways to tackle this problem is the CO2 capture and its utilization… read more here.
Keywords: frustrated lewis; adsorption activation; co2; lewis pairs ... See more keywords
Radiation-Synthesized Metal-Organic Frameworks with Ligand-Induced Lewis Pairs for Selective CO2 Electroreduction.
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DOI: 10.1002/smll.202408688
Abstract: The electrochemical activation of inert CO2 molecules through C─C coupling reactions under ambient conditions remains a significant challenge but holds great promise for sustainable development and the reduction of CO2 emission. Lewis pairs can capture… read more here.
Keywords: co2; synthesized metal; lewis pairs; radiation synthesized ... See more keywords
Dihydroazulene-vinylheptafulvene based photoswitchable lewis pairs for tunable H2 activation
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.03.251
Abstract: Abstract Photoswitchable catalysis involves alteration in the intrinsic catalytic properties of an active species through a reversible photochemical transformation. Herein, we report dihydroazulene-vinylheptafulvene (DHA-VHF) based photoswitchable frustrated Lewis pairs (FLPs) for reversible hydrogen activation. The… read more here.
Keywords: based photoswitchable; dihydroazulene vinylheptafulvene; vinylheptafulvene; lewis pairs ... See more keywords
The development of reaction kinetics for CO2 absorption into novel solvent systems: Frustrated Lewis pairs (FLPs)
Sign Up to like & getrecommendations! Published in 2020 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2020.117450
Abstract: Abstract Frustrated Lewis Pairs (FLPs) comprising sterically hindered Lewis acids and bases were developed and kinetic parameters for the homogenous reaction between CO2 and FLP dissolved in bromobenzene were obtained by using the stopped-flow method… read more here.
Keywords: lewis pairs; hindered lewis; sterically hindered; pairs flps ... See more keywords
Role of surface frustrated Lewis pairs on reduced CeO2(110) in direct conversion of syngas
Sign Up to like & getrecommendations! Published in 2020 at "Chinese Journal of Catalysis"
DOI: 10.1016/s1872-2067(20)63627-0
Abstract: Abstract Direct syngas conversion to light olefins on bifunctional oxide-zeolite (OX-ZEO) catalysts is of great interest to both academia and industry, but the role of oxygen vacancy (Vo) in metal oxides and whether the key… read more here.
Keywords: lewis pairs; conversion; role; syngas ... See more keywords
Porous Frustrated Lewis Pairs Catalyst Constructed on Defective Zirconium-Based Metal-Organic Frameworks for Hydrogenation Reactions with H2.
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DOI: 10.1021/acs.inorgchem.4c02470
Abstract: A porous metal-organic framework (MOF)-based frustrated Lewis pairs (FLPs) were prepared via a ligand replacement strategy to generate organic linker defects in zirconium-based MOF (MOF-808), thereby exposing Zr sites as Lewis acid. Due to the… read more here.
Keywords: frustrated lewis; catalyst; metal; lewis pairs ... See more keywords
Design of Borole- and Silylene-Based Frustrated Lewis Pairs for Dinitrogen Activation Promoted by Aromaticity: A Combined DFT and Machine Learning Study.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c02343
Abstract: In recent years, while main-group elements from the s- and p-block have emerged in the field of N2 activation, silylenes─despite their remarkable successes in the activation of diverse small molecules─remain unreported for N2 activation. Herein,… read more here.
Keywords: frustrated lewis; chemistry; machine learning; activation ... See more keywords