Increasing H2SO4 contents in disulfates cresting in the new hydrogenium-bis-hydrogendisulfate anion [H(HS2O7)2]−: Li2[S2O7]·H2SO4, Li[HS2O7], and Li[H(HS2O7)2]
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DOI: 10.1039/c6nj02388f
Abstract: The reactions of simple Li salts like sulfates, carbonates, and chlorides with fuming sulfuric acid or neat SO3 led to a couple of new acidic Li disulfates with varying H2SO4 : SO3 ratios, namely Li2[S2O7]·H2SO4 (orthorhombic, Pca21,… read more here.
Keywords: hydrogenium bis; li2 s2o7; new hydrogenium; s2o7 h2so4 ... See more keywords