Metal-Ligand-Anion Cooperation in C-H Bond Formation at Platinum(II).
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DOI: 10.1021/jacs.2c05096
Abstract: Thermolysis of [H(BPI)Pt(CH3)][OTf] (BPI = 1,3-bis(2-(4-tert-butyl)pyridylimino)isoindole) to release methane and form (BPI)Pt(OTf) is reported. Kinetic, mechanistic, and computational studies point to an unusual anion-assisted pathway that obviates the need for a higher oxidation state intermediate… read more here.
Keywords: bpi; anion cooperation; ligand anion; anion ... See more keywords