Compartmental ligand approach for constructing 3d–4f heterometallic [CuII5LnIII2] clusters: synthesis and magnetostructural properties
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DOI: 10.1039/c6ce02519f
Abstract: The employment of a reduced Schiff-base ligand, 1,3-bis(3-methoxy-salicylamino)-2-propanol (H3L), with the assistance of acetate anions led to the isolation of eight heptanuclear heterometallic complexes containing [Cu5Ln2] cores. Single-crystal X-ray diffraction analyses have been performed for… read more here.
Keywords: ligand approach; approach constructing; cuii cuii; cuii gdiii ... See more keywords
Dual ligand approach increases functional group tolerance in the Pd-catalysed C–H arylation of N-heterocyclic pharmaceuticals
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DOI: 10.1039/d2sc04911b
Abstract: The excellent functional group tolerance of the Suzuki–Miyaura cross-coupling reactions has been decisive for their success in the pharmaceutical industry. Highly diversified (hetero)aromatic scaffolds can be effectively coupled in the final step(s) of a convergent… read more here.
Keywords: group tolerance; functional group; dual ligand; ligand approach ... See more keywords