Aminotroponiminates: ligand-centred, reversible redox events under oxidative conditions in sodium and bismuth complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01019f
Abstract: A straightforward synthetic route to aminotroponate (AT) and aminotroponiminate (ATI) ligands with a ferrocenyl substituent at nitrogen is presented. Sodium derivatives have been synthesised and the first synthetic access to bismuth AT and ATI species… read more here.
Keywords: ligand centred; centred reversible; aminotroponiminates ligand; bismuth ... See more keywords
Ligand-centred redox activation of inert organoiridium anticancer catalystsâ€
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc00897d
Abstract: Organometallic complexes with novel activation mechanisms are attractive anticancer drug candidates. Here, we show that half-sandwich iodido cyclopentadienyl iridium(iii) azopyridine complexes exhibit potent antiproliferative activity towards cancer cells, in most cases more potent than cisplatin.… read more here.
Keywords: ligand centred; redox activation; organoiridium anticancer; activation ... See more keywords