Facile and high-yield synthesis of improved MIL-101(Cr) metal-organic framework with exceptional CO2 and H2S uptake; the impact of excess ligand-cluster
Sign Up to like & getrecommendations! Published in 2019 at "Microporous and Mesoporous Materials"
DOI: 10.1016/j.micromeso.2018.12.033
Abstract: Abstract The goal of this research was to investigate the effect of various cluster/ligand (X) and cluster/modulator (Y) ratios on the textural properties, reaction yield and gas uptake of MIL-101@M-X-Y. The results revealed that the… read more here.
Keywords: co2; mil 101; co2 h2s; yield ... See more keywords
Phosphine-Ligated Gold Clusters with Core+ exo Geometries: Unique Properties and Interactions at the Ligand-Cluster Interface.
Sign Up to like & getrecommendations! Published in 2018 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.8b00477
Abstract: Over recent years, research on the structures and properties of ligand-protected gold cluster molecules has gained significant interest. The crystal structure information accumulated to date has revealed the structural preference to adopt closed polyhedral geometries,… read more here.
Keywords: ligand cluster; gold clusters; core exo; gold ... See more keywords
Inorganic Ligands Sb3- and Bi3-: Synthesis and Crystal Structures of Complexes with Mixed-Ligand Cluster Cores {Re4Se3Sb}7+ and {Re4Se3Bi}7.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00246
Abstract: The reactions of ReI3, Se, and KCN with Sb2O3 or Bi2O3 at elevated temperature led to the formation of two new tetrahedral clusters with mixed-ligand cluster cores {Re4Se3Sb}7+ and {Re4Se3Bi}7+. They are the first examples… read more here.
Keywords: re4se3sb re4se3bi; ligand cluster; cores re4se3sb; cluster cores ... See more keywords