Ligand Configuration-Induced Manganese(II) Coordination Polymers: Syntheses, Crystal Structures, Sorption, and Magnetic Properties.
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DOI: 10.1021/acs.inorgchem.7b01657
Abstract: Three new coordination polymers, {[Mn3(pzbtz)2(Cl)2(H2O)2]·4H2O}n (1), {Mn2(pzbtz)(SO4)(H2O)3]·3H2O}n (2), and {[Mn3(pzbtz)3(H2O)3]·1.5DMA·2H2O}n (3), have been solvothermally synthesized with MnCl2/MnSO4 and a bitriazole ligand, 5'-(pyrazin-2-yl)-2H,4'H-3,3'-bi(1,2,4-triazole) (H2pzbtz), in different solvent systems. H2pzbtz shows different geometrical configurations and coordination modes,… read more here.
Keywords: coordination; coordination polymers; ligand configuration; configuration induced ... See more keywords