Exploring the influence of H-bonding and ligand constraints on thiolate ligated non-heme iron mediated dioxygen activation
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DOI: 10.1039/d4sc02787f
Abstract: Converting triplet dioxygen into a powerful oxidant is fundamentally important to life. The study reported herein quantitatively examines the formation of a well-characterized, reactive, O2-derived thiolate ligated FeIII-superoxo using low-temperature stopped-flow kinetics. Comparison of the… read more here.
Keywords: ligand constraints; thiolate ligated; dioxygen activation; activation ... See more keywords