Metal–Ligand Cooperation as Key in Formation of Dearomatized NiII–H Pincer Complexes and in Their Reactivity toward CO and CO2
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00160
Abstract: The unique synthesis and reactivity of [(RPNP*)NiH] complexes (1a,b), based on metal–ligand cooperation (MLC), are presented (RPNP* = deprotonated PNP ligand, R = iPr, tBu). Unexpectedly, the dearomatized complexes 1a,b were obtained by reduction of… read more here.
Keywords: pincer; ligand cooperation; metal ligand; reactivity ... See more keywords
Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b02902
Abstract: Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal–ligand cooperation of the manganese… read more here.
Keywords: deoxygenative hydrogenation; hydrogenation amides; metal; ligand cooperation ... See more keywords
Manganese(I)-Catalyzed H-P Bond Activation via Metal-Ligand Cooperation.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c10756
Abstract: Here we report that chiral Mn(I) complexes are capable of H-P bond activation. This activation mode enables a general method for the hydrophosphination of internal and terminal α,β-unsaturated nitriles. Metal-ligand cooperation, a strategy previously not… read more here.
Keywords: bond activation; ligand cooperation; metal ligand; activation ... See more keywords
Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal–Ligand Cooperation
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08491
Abstract: The development of catalysts for environmentally benign organic transformations is a very active area of research. Most of the catalysts reported so far are based on transition-metal complexes. In recent years, examples of catalysis by… read more here.
Keywords: ligand cooperation; hydrogenation; metal ligand; metal ... See more keywords
Formal oxidative addition of a C-H bond by a 16e iridium(i) complex involves metal-ligand cooperation.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc01885e
Abstract: The first example of oxidative addition of a C-H bond to a square planar d8-Iridium complex, without any external additive, such as an acid, is described. Our mechanistic investigations show that metal-ligand cooperation through aromatization-dearomatization… read more here.
Keywords: iridium complex; addition bond; ligand cooperation; metal ligand ... See more keywords
Recent developments on the transformation of CO2 utilising ligand cooperation and related strategies.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01609e
Abstract: A portfolio of value-added chemicals, fuels and building block compounds can be envisioned from CO2 on an industrial scale. The high kinetic and thermodynamic stabilities of CO2, however, present a significant barrier to its utilisation… read more here.
Keywords: transformation co2; cooperation; related strategies; ligand cooperation ... See more keywords