Bidentate N‐based Ligands for Highly Reusable, Ligand‐coordinated, Supported Pt Hydrosilylation Catalysts
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DOI: 10.1002/cctc.202000085
Abstract: A significant challenge in designing supported metal‐ligand catalysts for solution‐phase reactions is the stabilization of the metal active sites against leaching into solution. Here, we examine alkene hydrosilylation reactions as model systems to improve the… read more here.
Keywords: ligand coordinated; based ligands; metal; bidentate based ... See more keywords
Novel N6 trisbidentate ligand coordinated Ir(iii) complexes and their Ru(ii) analogs.
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DOI: 10.1039/c8dt03544j
Abstract: Novel N6-coordinated Ir(iii) complexes bearing polypyridyl ligands were synthesized and characterized. In comparison to their Ru(ii) analogs, these Ir(iii) complexes showed blue-shifted UV-vis absorption and emission spectra, but dramatically increased triplet lifetimes with much broader… read more here.
Keywords: novel trisbidentate; ligand coordinated; coordinated iii; iii complexes ... See more keywords
Two bis-ligand-coordinated Zn(ii)-MOFs for luminescent sensing of ions, antibiotics and pesticides in aqueous solutions
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DOI: 10.1039/d2ra00376g
Abstract: Two organometallic complexes with two and three-dimensional architectures were constructed by using multiple ligands and Zn(ii) ions: [Zn3(BTC)2(DTP)4(H2O)2]·(H2O)4 (Zn-1) (BTC = benzene-1,3,5-tricarboxylic acid and DTP = 3,5-di(1,2,4-triazol-1-yl)pyridine) and [Zn2(NTD)2(DTP)] (Zn-2) (NTD = 1,4-naphthalenedicarboxylic acid). The… read more here.
Keywords: antibiotics pesticides; ligand coordinated; two bis; bis ligand ... See more keywords