Two mixed-ligand coordination compounds: crystal structure and anti-liver cancer activity
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the Iranian Chemical Society"
DOI: 10.1007/s13738-018-1425-9
Abstract: Two 3D mixed-ligand coordination compounds, [Cd(1,3-bdc)(bmip)]n[1, H21,3-bdc = 1,3-benzenedicarboxylic acid, bmip = 1,3-bis(2-methyl-1H-imidazol-1-yl)propane] and [Cd(5-mpc)(bmip)]n (2, H25-mpc = 5-methylisophthalic acid), have been successfully synthesized under hydrothermal conditions and characterized successfully by single crystal X-ray analysis.… read more here.
Keywords: coordination compounds; two mixed; mixed ligand; liver cancer ... See more keywords
Ligand coordination- and dissociation-induced divergent allylic alkylations using alkynes
Sign Up to like & getrecommendations! Published in 2021 at "Chem"
DOI: 10.1016/j.chempr.2021.02.018
Abstract: Summary In transition metal catalysis, the nature of ligand coordination plays a vital role in defining the reactivity of the catalytic system. Achieving multi-substrate coordination and coupling by leveraging dynamic ligand dissociation is rare. Here,… read more here.
Keywords: divergent allylic; induced divergent; coordination; dissociation ... See more keywords
Biomimetic poly(γ-glutamic acid) hydrogels based on iron (III) ligand coordination for cartilage tissue engineering.
Sign Up to like & getrecommendations! Published in 2020 at "International journal of biological macromolecules"
DOI: 10.1016/j.ijbiomac.2020.11.105
Abstract: For the problems in the research on differentiation of mesenchymal stem cells (BMSCs), such as poor differentiation tendency and low differentiation efficiency, a novel photo-crosslinked extracellular matrix (ECM) inspired double network hydrogel that composed of… read more here.
Keywords: poly glutamic; glutamic acid; differentiation; cartilage tissue ... See more keywords
Decoupling Bulk Mechanics and Mono- and Multivalent Ion Transport in Polymers Based on Metal–Ligand Coordination
Sign Up to like & getrecommendations! Published in 2018 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.8b02633
Abstract: Decoupling bulk mechanics and ion conduction in conventional ion conducting polymers is challenging due to their mutual dependence on segmental chain dynamics. Polymers based on dynamic metal–ligand coordination are promising materials toward this aim. This… read more here.
Keywords: polymers based; metal ligand; ion; mechanics ... See more keywords
Dynamic Metal-Ligand Coordination-Assisted Ionogels for Deformable Alternating Current Electroluminescent Devices.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.3c03812
Abstract: Overcoming the trade-off between the mechanical robustness and conductivity of ionic conductors is a crucial challenge for deformable ionotronics. In this work, we propose a simple but effective gelation strategy for selectively improving the mechanical… read more here.
Keywords: ligand coordination; dynamic metal; alternating current; metal ligand ... See more keywords
A facile approach to thermomechanically enhanced fatty acid-containing bioplastics using metal–ligand coordination
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Chemistry"
DOI: 10.1039/c9py01479a
Abstract: Dynamic metal–ligand coordination creates physical crosslinking and thus improves chain entanglements for enhancing the thermomechanical properties of biobased polymers. read more here.
Keywords: facile approach; metal ligand; ligand coordination;
Changes in ligand coordination mode induce bimetallic C-C coupling pathways.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00322h
Abstract: Carbon-carbon coupling is one of the most powerful tools in the organic synthesis arsenal. Known methodologies primarily exploit monometallic Pd0/PdII catalytic mechanisms to give new C-C bonds. Bimetallic C-C coupling mechanisms that involve a PdI/PdII… read more here.
Keywords: ligand coordination; coordination; bimetallic coupling; changes ligand ... See more keywords
Mn(II) and Co(II) mixed-ligand coordination compounds with acesulfame and 3-aminopyridine: synthesis and structural properties
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2021.1888083
Abstract: Abstract Two mixed ligand complexes containing acesulfame (acs) and 3-aminopyridine (3-ap) ligands of Mn(II) and Co(II) were synthesized. The obtained compounds were characterized by various analysis methods. The geometries of complexes, C18H28MnN6O12S2 (1) and C18H32CoN6O14S2… read more here.
Keywords: coordination compounds; coordination; compounds acesulfame; acesulfame aminopyridine ... See more keywords