Enhanced resistance to poisoning of Pd in alkynes semi‐hydrogenation by metal–ligand electronic interactions
Sign Up to like & getrecommendations! Published in 2024 at "AIChE Journal"
DOI: 10.1002/aic.18687
Abstract: Given that the retention of nitrogen readily renders active site poisoning, designing versatile catalysts characterized by notable selectivity and even resistance to poisoning for alkyne semi‐hydrogenation under nitrogen‐containing conditions is considerably challenging. In this article,… read more here.
Keywords: hydrogenation; ligand electronic; resistance poisoning; semi hydrogenation ... See more keywords
Effect of Ligand on the Electronic State of Gold in Ligand-Protected Gold Clusters Elucidated by X-ray Absorption Spectroscopy
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DOI: 10.1021/acs.jpcc.0c09369
Abstract: Gold (Au) clusters with well-defined geometrical structures have attracted substantial attention due to their unique optical and catalytic properties, which are drastically changed by the ligands, ... read more here.
Keywords: ligand electronic; spectroscopy; ligand; effect ligand ... See more keywords
Lewis Acid Effects on Calculated Ligand Electronic Parameters
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DOI: 10.1021/acs.organomet.0c00407
Abstract: Adding Lewis acids to coordinated ligands can impart systematic changes to their properties. We computationally explored the effects of acid-induced changes to the donor strength (Tolman electronic... read more here.
Keywords: lewis acid; calculated ligand; ligand electronic; acid effects ... See more keywords