Effect of Ligand on the Electronic State of Gold in Ligand-Protected Gold Clusters Elucidated by X-ray Absorption Spectroscopy
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c09369
Abstract: Gold (Au) clusters with well-defined geometrical structures have attracted substantial attention due to their unique optical and catalytic properties, which are drastically changed by the ligands, ... read more here.
Keywords: ligand electronic; spectroscopy; ligand; effect ligand ... See more keywords
Lewis Acid Effects on Calculated Ligand Electronic Parameters
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00407
Abstract: Adding Lewis acids to coordinated ligands can impart systematic changes to their properties. We computationally explored the effects of acid-induced changes to the donor strength (Tolman electronic... read more here.
Keywords: lewis acid; calculated ligand; ligand electronic; acid effects ... See more keywords