Remodeling of N-Heterocyclic Iminato Ligand Frameworks for the Facile Synthesis of Isoureas from Alcohols and Carbodiimides Promoted by Organoactinide (Th, U) Complexes
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DOI: 10.1021/acsomega.1c01836
Abstract: A new class of actinide complexes [(L)An(N{SiMe3}2)3] (An = Th or U) (Th1–Th3 and U1–U3) supported by highly nucleophilic seven-membered N-heterocyclic iminato ligands were synthesized and fully characterized by single-crystal X-ray diffraction. These complexes were… read more here.
Keywords: heterocyclic iminato; remodeling heterocyclic; ligand frameworks; iminato ligand ... See more keywords