Hydrothermal Preparation, Crystal Structure, Photophysical Properties and Theoretical Calculation of a Cu(II) Complex
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Chemical Crystallography"
DOI: 10.1007/s10870-020-00837-2
Abstract: Abstract A novel Cu(II) compound [CuL 2 ]·2H 2 O was synthesized by hydrothermal methods, and its crystal structure was determined by single-crystal X-ray diffraction. The title compound crystallized in the monoclinic space group P… read more here.
Keywords: crystal structure; hydrothermal preparation; compound; structure ... See more keywords
Insight into the Ligand-to-Ligand Charge-Transfer Process in Rare-Earth-Metal Diradical Complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00900
Abstract: While a ligand-to-ligand charge-transfer (LLCT) process is an important way to understand the interactions between metal-bridged radicals for late-transition-metal complexes, there is little clear and evident observation of the LLCT process for rare-earth-metal complexes. In… read more here.
Keywords: ligand; earth metal; ligand ligand; rare earth ... See more keywords
Dinuclear ligand-to-ligand charge transfer complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03385b
Abstract: The synthesis and characterization of dinuclear ligand-to-ligand charge transfer complexes are described. Each complex is comprised of square-planar platinum(II) coordinated to a 3-tert-butyl-orthocatecholate donor and a 4,4'-di-tert-butyl-2,2'-bipyridine acceptor. Both complexes exhibit donor → acceptor ligand-to-ligand… read more here.
Keywords: ligand ligand; charge transfer; ligand charge; ligand ... See more keywords
Square-Planar Heteroleptic Complexes of α-Diimine-NiII-Catecholate Type: Intramolecular Ligand-to-Ligand Charge Transfer
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26154622
Abstract: Two heteroleptic NiII complexes combined the redox-active catecholate and 2,2′- bipyridine ligand platforms were synthesized to observe a photoinduced intramolecular ligand-to-ligand charge transfer (LL’CT, HOMOcatecholate → LUMOα-diimine). A molecular design of compound [NiII(3,6-Cat)(bipy)]∙CH3CN (1) on… read more here.
Keywords: intramolecular ligand; ligand charge; square planar; ligand ... See more keywords