Articles with "ligand mediated" as a keyword



Synthesis of Elastic Metallic Nickel by Solvent‐Ligand‐Mediated Reductive Assembly

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Published in 2025 at "Advanced Science"

DOI: 10.1002/advs.202508160

Abstract: Metallic foams hold significant promise as lightweight structural materials. However, most conventional metallic foams are inherently rigid and brittle, frequently undergoing structural collapse. There is an urgent demand to develop cost‐effective, facile‐to‐synthesize metallic foams with… read more here.

Keywords: metallic nickel; solvent ligand; synthesis elastic; ligand mediated ... See more keywords

Relative contribution of molecular mechanisms to cumulative ligand-mediated downregulation of GRα.

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Published in 2022 at "Biochemical and biophysical research communications"

DOI: 10.1016/j.bbrc.2022.02.102

Abstract: Central to the pharmacological use of glucocorticoids (GCs) is the availability of the glucocorticoid receptor alpha (GRα). However, chronic GC therapy often results in the ligand-mediated downregulation of the GRα, and the subsequent development of… read more here.

Keywords: mediated downregulation; relative contribution; contribution molecular; molecular mechanisms ... See more keywords

Expanding the Toolbox of Oxidants: Controllable Etching of Ultrasmall Au Nanoparticles toward Tailorable NIR-II Luminescence and Ligand-Mediated Biodistribution and Clearance.

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Published in 2024 at "Analytical chemistry"

DOI: 10.1021/acs.analchem.4c04326

Abstract: Oxidant-driven and controllable etching of small-sized nanoparticles (NPs, d < 3 nm) and tailorable modulation of their optical properties are challenging due to the high reactivity and complicated surface chemistry. Herein, we present a facile… read more here.

Keywords: chemistry; controllable etching; etching ultrasmall; ligand mediated ... See more keywords
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Ligand-Mediated Phase Control in Colloidal AgInSe2 Nanocrystals

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Published in 2020 at "Chemistry of Materials"

DOI: 10.1021/acs.chemmater.9b05163

Abstract: Synthetic studies of colloidal nanoparticles that crystallize in metastable structures represent an emerging area of interest in the development of novel functional materials, as metastable nanomat... read more here.

Keywords: mediated phase; phase control; control colloidal; colloidal aginse2 ... See more keywords

Hydrophilic BIPHEPHOS Ligand for Pd-Mediated Cysteine Allylation of Peptides and Proteins in Water

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Published in 2025 at "Organic Letters"

DOI: 10.1021/acs.orglett.5c04112

Abstract: The selective and natural post-translational modification of peptides and proteins under biocompatible conditions remains a challenge. Herein, we report a hydrophilic variant of the BIPHEPHOS ligand featuring diethyl phosphonates as solubilizing groups, which were found… read more here.

Keywords: hydrophilic biphephos; ligand mediated; biphephos ligand; peptides proteins ... See more keywords

Ligand-Mediated Band Engineering in Bottom-Up Assembled SnTe Nanocomposites for Thermoelectric Energy Conversion

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Published in 2019 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.9b01394

Abstract: The bottom-up assembly of colloidal nanocrystals is a versatile methodology to produce composite nanomaterials with precisely tuned electronic properties. Beyond the synthetic control over crystal domain size, shape, crystal phase, and composition, solution-processed nanocrystals allow… read more here.

Keywords: engineering; bottom; band; ligand mediated ... See more keywords

Unveiling Ligand-Mediated Phase Engineering Mechanism in Two-Dimensional Transition Metal Chalcogenides through Coordination Geometry Control

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Published in 2024 at "Journal of Materials Chemistry A"

DOI: 10.1039/d4ta00326h

Abstract: While metastable metallic phases of group-VI transition metal dichalcogenides (TMDCs) nanosheets exhibit intriguing and unprecedented characteristics, the development of reliable synthetic methodologies, particularly in direct solution-based synthesis, remains a challenge... read more here.

Keywords: ligand mediated; transition metal; unveiling ligand; geometry ... See more keywords

Ligand-mediated CsPbBr x I3− x /SiO2 quantum dots for red, stable and low-threshold amplify spontaneous emission

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Published in 2022 at "Nanotechnology"

DOI: 10.1088/1361-6528/ac64b0

Abstract: The red-emitting perovskite material has received widespread attention as a long-wavelength optical gain media. But the easy phase change in the air limits its practical application. Herein, red CsPbBr x I3−x /SiO2 quantum dots (QDs)… read more here.

Keywords: ligand mediated; quantum dots; cspbbr sio2; sio2 quantum ... See more keywords

Nature of Excitons and Their Ligand-Mediated Delocalization in Nickel Dihalide Charge-Transfer Insulators

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Published in 2024 at "Physical Review X"

DOI: 10.1103/physrevx.14.031007

Abstract: The fundamental optical excitations of correlated transition-metal compounds are typically identified with multielectronic transitions localized at the transition-metal site, such as dd transitions. In this vein, intense interest has surrounded the appearance of sharp, below-band-gap… read more here.

Keywords: charge transfer; ligand mediated; magnetic order; transfer ... See more keywords

Receptor activator of nuclear factor-κB ligand-mediated osteoclastogenesis signaling pathway and related therapeutic natural compounds

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Published in 2022 at "Frontiers in Pharmacology"

DOI: 10.3389/fphar.2022.1043975

Abstract: Osteoclast is a hematopoietic precursor cell derived from the mononuclear macrophage cell line, which is the only cell with bone resorption function. Its abnormal activation can cause serious osteolysis related diseases such as rheumatoid arthritis,… read more here.

Keywords: nuclear factor; receptor activator; activator nuclear; natural compounds ... See more keywords