Novel Triazole Thiole ligand and some of its metal chelates: Synthesis, structure charactertization, thermal behavior in comparison withcomputational caculations andbiological activities
Sign Up to like & getrecommendations! Published in 2019 at "Computational biology and chemistry"
DOI: 10.1016/j.compbiolchem.2018.12.008
Abstract: Structural and molecular properties of HL, 4-amino-5-(2,2-dichloro-1-methylcyclopropyl)-4H-1,2,4-triazole-3-thiol toward the transition metal ions namely Fe(III), Co(II) and Ni(II) had been studied using elemental analyses, magnetic, electronic, FT- IR, 1H-NMR and Thermal analyses (TGA and DTA). The… read more here.
Keywords: thiole ligand; metal chelates; metal; ligand metal ... See more keywords
Visible-Light Activation of a Dissolved Organic Matter-TiO2 Complex Mediated via Ligand-to-Metal Charge Transfer.
Sign Up to like & getrecommendations! Published in 2022 at "Environmental science & technology"
DOI: 10.1021/acs.est.2c02975
Abstract: Given the widespread use of TiO2, its release into aquatic systems and complexation with dissolved organic matter (DOM) are highly possible, making it important to understand how such interactions affect photocatalytic activity under visible light.… read more here.
Keywords: organic matter; ligand metal; dissolved organic; tio2 ... See more keywords
Photoinduced Ligand-to-Metal Charge Transfer (LMCT) of Fe Alkoxide Enabled C-C Bond Cleavage and Amination of Unstrained Cyclic Alcohols.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.1c04365
Abstract: We report an alkoxy radical process for the C-C bond cleavage and functionalization of unstrained tertiary and secondary cyclic alcohols. In the absence of a chlorine atom, the readily available iron catalysts [Fe(OBu-t)3 or Fe(acac)3/t-BuONa]… read more here.
Keywords: ligand metal; bond cleavage; cyclic alcohols; transfer ... See more keywords
Dual-Ligand Fe-Metal Organic Framework Based Robust High Capacity Li Ion Battery Anode and Its Use in a Flexible Battery Format for Electro-Thermal Heating
Sign Up to like & getrecommendations! Published in 2019 at "ACS Applied Energy Materials"
DOI: 10.1021/acsaem.9b00688
Abstract: Metal organic frameworks (MOFs) have been attracting recent scientific attention as battery electrode materials due to the ease of tailoring their structure, porosity, and properties by varying the... read more here.
Keywords: organic framework; ligand metal; battery; dual ligand ... See more keywords
Mixed-Ligand Metal-Organic Frameworks for All-in-One Theranostics with Controlled Drug Delivery and Enhanced Photodynamic Therapy.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c06873
Abstract: Mixed-ligand metal-organic frameworks (MOFs) multiply the properties and improve the versatility of conventional MOFs for theranostic applications. A tumor targeting and tumoral microenvironment-responsive system is significant for specific and efficient cancer theranostics. Herein, we report… read more here.
Keywords: ligand metal; therapy; ligand; metal organic ... See more keywords
Dual Intrareticular Oxidation of Mixed-Ligand Metal-Organic Frameworks for Stepwise Electrochemiluminescence.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c00001
Abstract: This work presents a mixed-ligand metal-organic framework (m-MOF) integrated with two ligands, one as a luminophore and the other as a coreactant, on one metal node for self-enhanced electrochemiluminescence (ECL). Both 9,10-di(p-carboxyphenyl)anthracene (DPA) and 1,4-diazabicyclo[2.2.2]octane… read more here.
Keywords: electrochemiluminescence; oxidation; metal organic; ligand metal ... See more keywords
Tuning dimensionality between 2D and 1D MOFs by lanthanide contraction and ligand-to-metal ratio
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d0nj04055j
Abstract: 2D/1D dimensionality tuning in LnMOFs is related to both (i) ligand-to-metal ratio and (ii) lanthanide contraction, this is only possible with Er/Tm, lighter lanthanides e.g. Pr only produced 2D MOFs, despite different ligand-to-metal ratios were… read more here.
Keywords: ligand metal; ligand; lanthanide contraction; metal ratio ... See more keywords
Visible-light-induced ligand to metal charge transfer excitation enabled phosphorylation of aryl halides.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc01858b
Abstract: We herein described a visible light induced nickel(II)-catalyzed cross-coupling of secondary phosphine oxides with aryl halides. The Ni(I) species and chlorine atom radical Cl˙ were generated via the ligand to metal charge transfer (LMCT) process… read more here.
Keywords: light induced; visible light; ligand metal; aryl halides ... See more keywords
Novel Coumarin-Thiadiazole Hybrids and Their Cu(II) and Zn(II) Complexes as Potential Antimicrobial Agents and Acetylcholinesterase Inhibitors
Sign Up to like & getrecommendations! Published in 2021 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms22189709
Abstract: A series of coumarin-thiadiazole hybrids and their corresponding Cu(II) and Zn(II) complexes were synthesized and characterized with the use of spectroscopic techniques. The results obtained indicate that all the coumarin-thiadiazole hybrids act as bidentate chelators… read more here.
Keywords: novel coumarin; thiadiazole hybrids; coumarin thiadiazole; ligand metal ... See more keywords
Development of New Azomethine Metal Chelates Derived from Isatin: DFT and Pharmaceutical Studies
Sign Up to like & getrecommendations! Published in 2022 at "Materials"
DOI: 10.3390/ma16010083
Abstract: Through the condensation of isatin (indoline-2, 3-dione) and aniline in a 1:1 ratio, a Schiff base ligand was synthesized and characterized via (1H-NMR, mass, IR, UV-Vis) spectra. Elemental analyses, spectroscopy (1H-NMR, mass, UV-Vis), magnetic susceptibility,… read more here.
Keywords: metal complexes; development new; ligand metal; geometry ... See more keywords
Pt-Chitosan-TiO2 for Efficient Photocatalytic Hydrogen Evolution via Ligand-to-Metal Charge Transfer Mechanism under Visible Light
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27154673
Abstract: The Pt-chitosan-TiO2 charge transfer (CT) complex was synthesized via the sol-gel and impregnation method. The synthesized photocatalysts were thoroughly characterized, and their photocatalytic activity were evaluated toward H2 production through water reduction under visible-light irradiation.… read more here.
Keywords: charge transfer; ligand metal; chitosan tio2; visible light ... See more keywords