Nickel(ii) complexes of a 3N ligand as a model for diketone cleaving unusual nickel(ii)-dioxygenase enzymes.
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DOI: 10.1039/c7dt04739h
Abstract: Diketone substrate bound nickel(ii) complexes of 2,6-bis(1-methylbenzimidazolyl)pyridine have been synthesized and characterized as relevant active site models for unusual diketone cleaving Ni(ii)-dependent enzymes Ni-ARD and DKDO. The average Ni-Npy/benzim bond distances (2.050-2.107 Å) of model… read more here.
Keywords: complexes ligand; diketone; ligand model; nickel complexes ... See more keywords
Interspecies-Extrapolated Biotic Ligand Model to Predict Arsenate Toxicity to Terrestrial Plants with Consideration of Cell Membrane Surface Electrical Potential
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DOI: 10.3390/toxics10020078
Abstract: Arsenic is a metalloid that is highly toxic to living organisms in the environment. In this study, toxicity caused by inorganic arsenate (As(V)) to terrestrial plants, such as barley Hordeum vulgare and wheat Triticum aestivum,… read more here.
Keywords: membrane; biotic ligand; toxicity; terrestrial plants ... See more keywords