From 8- to 18-Cluster Electrons Superatoms: Evaluation via DFT Calculations of the Ligand-Protected W@Au12(dppm)6 Cluster Displaying Distinctive Electronic and Optical Properties.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03771
Abstract: The iconic W@Au12 icosahedral bare cluster reaches the favorable closed-shell superatomic electron configuration 1S2 1P6 1D10, making it an 18-cluster electron (18-ce) superatom. Here, we pursue the evaluation of a ligand-protected counterpart based on the construction of… read more here.
Keywords: au12 dppm; ligand protected; dppm; protected au12 ... See more keywords
Locating Hydrides in Ligand-Protected Copper Nanoclusters by Deep Learning.
Sign Up to like & getrecommendations! Published in 2021 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c14618
Abstract: Hydrides play an important role in constructing atomically precise metal nanoclusters and nanoparticles. They occupy both the interstitial sites inside the metal cores and the interfacial sites between the surface of the metal core and… read more here.
Keywords: locating hydrides; deep learning; copper nanoclusters; ligand protected ... See more keywords
Linear Size Contraction of Ligand Protected Ag29 Clusters by Substituting Ag with Cu.
Sign Up to like & getrecommendations! Published in 2020 at "ACS nano"
DOI: 10.1021/acsnano.0c05082
Abstract: There are only a few examples of atomically precise, ligand protected, bimetallic coinage metal clusters in which molecular structure remains essentially unchanged over a wide composition range starting from the corresponding homometallic species. Such model… read more here.
Keywords: size contraction; protected ag29; ligand protected; linear size ... See more keywords
Towards elucidating structure of ligand-protected nanoclusters.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt01418d
Abstract: Ligand-protected metal nanoclusters (NCs) are organic-inorganic nanostructures, exhibiting high stability at specific "magic size" compositions and tunable properties that make them promising candidates for a wide range of nanotechnology-based applications. Synthesis and characterization of these… read more here.
Keywords: elucidating structure; ligand protected; structure ligand; towards elucidating ... See more keywords
Nanostructured surfaces from ligand-protected metal nanoparticles.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt02822c
Abstract: Nanostructuring surfaces with metal atoms or clusters represents a promising approach to create materials with unique electronic/magnetic properties and improved chemical reactivity. By means of plasma sputtering and mass spectrometric techniques, the deposition of precisely… read more here.
Keywords: protected metal; metal nanoparticles; nanostructured surfaces; metal ... See more keywords
Crystal structure of bulky-ligand-protected Au24(S-C4H9)16.
Sign Up to like & getrecommendations! Published in 2022 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229622006738
Abstract: Atomically precise thiolate-protected gold nanomolecules have attracted interest due to their distinct electronic and chemical properties. The structure of these nanomolecules is important for understanding their peculiar properties. Here, we report the X-ray crystal structure… read more here.
Keywords: ligand protected; structure; structure bulky; au24 c4h9 ... See more keywords