Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.04.062
Abstract: Abstract The ligand-redistribution reactions of aryl- and alkoxy-hydrosilanes can potentially cause the formation of gaseous hydrosilanes, which are flammable and pyrophoric. The ability of generic nucleophiles to initiate the ligand-redistribution reaction of commonly used hydrosilane… read more here.
Keywords: induced ligand; reactions alkoxy; ligand rearrangement; ligand redistribution ... See more keywords
Intracluster ligand rearrangement: an NMR-based thermodynamic study
Sign Up to like & getrecommendations! Published in 2023 at "Nanoscale"
DOI: 10.1039/d3nr00360d
Abstract: Ligand and metal exchange reactions are powerful methods to tailor the properties of atomically precise metal nanoclusters. Hence, a deep understanding of the mechanisms behind the dynamics that rule the ligand monolayer is crucial for… read more here.
Keywords: intracluster; ligand rearrangement; intracluster ligand; nmr based ... See more keywords