Ligand Relay Catalysis Enables Asymmetric Migratory Reductive Acylation of Olefins or Alkyl Halides.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10785
Abstract: Design of ligands in transition-metal catalyzed reactions is challenging, especially in asymmetric transformations. With each step in the catalytic cycle promoted by its privileged ligand and different steps well-connected by dynamic ligand exchange, synergistic combination… read more here.
Keywords: enables asymmetric; catalysis enables; alkyl halides; acylation ... See more keywords
Ligand relay catalysis for cobalt-catalyzed sequential hydrosilylation and hydrohydrazidation of terminal alkynes
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DOI: 10.1038/s41467-022-28285-w
Abstract: Sequential double hydrofunctionalizationalization of alkynes is a powerful method to construct useful vicinal compounds. Herein, we report a cobalt-catalyzed sequential hydrosilylation/hydrohydrazidation of alkynes to afford 1,2- N,Si compounds via ligand relay catalysis. A phenomenon of… read more here.
Keywords: sequential hydrosilylation; hydrosilylation hydrohydrazidation; cobalt catalyzed; relay catalysis ... See more keywords