Host–guest driven ligand replacement on monodisperse inorganic nanoparticles† †Electronic supplementary information (ESI) available: Experimental and characterization (NMR, TGA, XPS, DLS and XRD). See DOI: 10.1039/c7nr02199b
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DOI: 10.1039/c7nr02199b
Abstract: We demonstrate that crown ether-assisted ligand replacement on Fe3O4 NPs using halide salts leads to quantitative stripping of an existing stabilizer shell with unprecedented (complete) efficiency; this allows subsequent re-grafting of functional ligands at maximal… read more here.
Keywords: replacement; replacement monodisperse; driven ligand; ligand replacement ... See more keywords
A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction.
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DOI: 10.1039/c9cc05236d
Abstract: A luminescent edge-interlocked heteroleptic metallocage based on Cu3(pyrazolate)3 was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations… read more here.
Keywords: luminescent edge; heteroleptic metallocage; ligand replacement; metallocage ... See more keywords
Magnetic Nanoparticle-Based Ligand Replacement Strategy for Chemical Luminescence Determination of Cholesterol
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DOI: 10.3389/fchem.2020.601636
Abstract: Determination of serum cholesterol (Chol) is important for disease diagnosis, and has attracted great attention during the last few decades. Herein, a new magnetic nanoparticle-based ligand replacement strategy has been presented for chemical luminescence detection… read more here.
Keywords: chemical luminescence; magnetic nanoparticle; ligand replacement; chol ... See more keywords