Capped Keggin Type Polyoxometalate-Based Inorganic-Organic Hybrids Involving In Situ Ligand Transformation as Supercapacitors and Efficient Electrochemical Sensors for Detecting Cr(VI).
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03097
Abstract: To construct polyoxometalate-based complexes as electrode materials for supercapacitors and electrochemical sensors, we intentionally used in situ ligand transformation during the reaction. Two complexes based on polyoxometalates capped by zinc ions, H{Zn4(DIBA)4[(DIBA)(HPO2)]2(α-PMoVI8MoV4O40Zn2)} (1) and [ε-PMoV8MoVI4O37(OH)3Zn4(HDBIBA)2]·6H2O… read more here.
Keywords: ligand transformation; polyoxometalate based; efficient electrochemical; situ ligand ... See more keywords
Three polyoxometalate-tuned copper complexes based on in situ ligand transformation: syntheses, structures, and properties
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1825698
Abstract: Abstract Depending on the in situ ligand transformation of 3,5-di(1,2,4-triazol-1-yl)benzonitrile (DTCN) to 3,5-di(1,2,4-triazol-1-yl)benzoic acid (DTCA) under hydrothermal condition, three polyoxometalate-based copper complexes, [CuI 4CuII 2(OH)2(H2O)4(DTCA)4(HPMoVI 10MoV 2O39)] (1), [Cu4(OH)2(H2O)4(DTCA)2(SiW12O40)]·11H2O (2), and {Cu2Cl(H2O)(HDTCA)2[CrMo6(OH)6O18)]}·4H2O (3), have been… read more here.
Keywords: situ ligand; three polyoxometalate; copper complexes; ligand transformation ... See more keywords