Tuning acylthiourea ligands in Ru(II) catalysts for altering the reactivity and chemoselectivity of transfer hydrogenation reactions, and synthesis of 3-isopropoxy-1H-indole through a new synthetic approach
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.121087
Abstract: Abstract Ru(II)-p-cymene complexes (1–3) containing picolyl based pseudo-acylthiourea ligands (L1-L3) were synthesized and characterized. The crystallographic study confirmed the molecular structures of all the ligands (L1-L3) and complex 3. The catalytic activity of the complexes… read more here.
Keywords: chemoselectivity; ligands catalysts; reactivity; tuning acylthiourea ... See more keywords
Cobalt complexes of pyrrolecarboxamide ligands as catalysts in nitro reduction reactions: influence of electronic substituents on catalysis and mechanistic insights
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DOI: 10.1039/c6qi00389c
Abstract: This work presents two square-planar Co(III) complexes within a N4 coordination sphere created by two related pyrrolecarboxamide ligands. Both complexes functioned as catalysts for the hydrazine-mediated reduction of aromatic, heterocyclic, as well as aliphatic nitro… read more here.
Keywords: reduction; pyrrolecarboxamide ligands; ligands catalysts; cobalt complexes ... See more keywords