Slower Removing Ligands of Metal Organic Frameworks Enables Higher Electrocatalytic Performance of Derived Nanomaterials.
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DOI: 10.1002/smll.202002210
Abstract: The widely used route of high-temperature pyrolysis for transformation of Prussian blue analogs (PBAs) to functional nanomaterials leads to the fast removal of CN- ligands, and thus the formation of large metal aggregates and the… read more here.
Keywords: slower removing; metal organic; oxygen vacancies; ligands metal ... See more keywords
Application of Hemilabile Ligands to “At-Metal Switching” Hydrogenation Catalysis
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DOI: 10.1021/acs.organomet.0c00562
Abstract: The paper describes the development of switchable catalysts: i.e., precatalysts that are activated by a reagent and the resulting active catalyst can be shut off with a second reagent. A concept is... read more here.
Keywords: switching hydrogenation; application hemilabile; hemilabile ligands; hydrogenation catalysis ... See more keywords
Isonitriles as supporting and non-innocent ligands in metal catalysis.
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DOI: 10.1039/d0cs00223b
Abstract: Isonitriles, being competent σ-donors, show a strong aptitude to form transition-state metal complexes. Nevertheless, until the end of the last century, few metal-isonitrile catalyzed processes were known. Only more recently, scientists recognized the considerable potential… read more here.
Keywords: isonitriles supporting; metal catalysis; catalysis; ligands metal ... See more keywords